FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2759333228> ?p ?o ?g. }

• W2759333228 endingPage "77" @default.
• W2759333228 startingPage "69" @default.
• W2759333228 abstract "The chemical degradation of poly(2,5-(4,4’-(hexafluoropropylidene)diphenyl)-1,3,4-oxadiazole) (F-POD) was studied in wet acidic media using a variety of analytical techniques. It was found that in aqueous acidic solution, F-POD degradation increased with higher acidity (lower pH) and can reach levels of up to 20% in mild acidic conditions (pH 5.5). Furthermore, residual water present in chloroform was found to be capable of inducing degradation in the fluorinated polymer as well. A mechanistic explanation of the hydrolysis is proposed, which implicates the electron withdrawing effect of the hexafluoroisopropylidene group in the oxadiazole ring opening. The initially linear polymer is suggested to be transformed into a bi- or three-dimensional polymer (i.e., a branched or cross-linked structure) due to the attack of 1,3,4-oxadiazole ring by carboxylic hydrazide, causing a considerable loss of its solubility in organic solvents. Finally, we demonstrate that F-POD is susceptible to cross-link via relatively simple chemistry." @default.
• W2759333228 created "2017-10-06" @default.
• W2759333228 creator A5046950466 @default.
• W2759333228 creator A5062229940 @default.
• W2759333228 creator A5085538607 @default.
• W2759333228 creator A5089803047 @default.
• W2759333228 date "2017-12-01" @default.
• W2759333228 modified "2023-09-23" @default.
• W2759333228 title "Degradation of fluorinated polyoxadiazole in wet acidic media" @default.
• W2759333228 cites W1555165582 @default.
• W2759333228 cites W1809543053 @default.
• W2759333228 cites W1973044071 @default.
• W2759333228 cites W1974350851 @default.
• W2759333228 cites W1976075691 @default.
• W2759333228 cites W1983318279 @default.
• W2759333228 cites W1985959550 @default.
• W2759333228 cites W1992757661 @default.
• W2759333228 cites W1996273492 @default.
• W2759333228 cites W1996940775 @default.
• W2759333228 cites W1998521582 @default.
• W2759333228 cites W2002664733 @default.
• W2759333228 cites W2007860802 @default.
• W2759333228 cites W2008469040 @default.
• W2759333228 cites W2014917029 @default.
• W2759333228 cites W2016464272 @default.
• W2759333228 cites W2020006305 @default.
• W2759333228 cites W2025117529 @default.
• W2759333228 cites W2033053348 @default.
• W2759333228 cites W2034659717 @default.
• W2759333228 cites W2044306313 @default.
• W2759333228 cites W2044349344 @default.
• W2759333228 cites W2055645754 @default.
• W2759333228 cites W2059760146 @default.
• W2759333228 cites W2064912816 @default.
• W2759333228 cites W2067681696 @default.
• W2759333228 cites W2069062879 @default.
• W2759333228 cites W2077889388 @default.
• W2759333228 cites W2081073414 @default.
• W2759333228 cites W2087570601 @default.
• W2759333228 cites W2094183776 @default.
• W2759333228 cites W2095649603 @default.
• W2759333228 cites W2159977492 @default.
• W2759333228 cites W2161598928 @default.
• W2759333228 cites W2294707952 @default.
• W2759333228 cites W2326639051 @default.
• W2759333228 cites W2334679709 @default.
• W2759333228 cites W979985306 @default.
• W2759333228 doi "https://doi.org/10.1016/j.polymdegradstab.2017.09.021" @default.
• W2759333228 hasPublicationYear "2017" @default.
• W2759333228 type Work @default.
• W2759333228 sameAs 2759333228 @default.
• W2759333228 citedByCount "4" @default.
• W2759333228 countsByYear W27593332282018 @default.
• W2759333228 countsByYear W27593332282021 @default.
• W2759333228 countsByYear W27593332282022 @default.
• W2759333228 countsByYear W27593332282023 @default.
• W2759333228 crossrefType "journal-article" @default.
• W2759333228 hasAuthorship W2759333228A5046950466 @default.
• W2759333228 hasAuthorship W2759333228A5062229940 @default.
• W2759333228 hasAuthorship W2759333228A5085538607 @default.
• W2759333228 hasAuthorship W2759333228A5089803047 @default.
• W2759333228 hasConcept C124681953 @default.
• W2759333228 hasConcept C137776501 @default.
• W2759333228 hasConcept C155574463 @default.
• W2759333228 hasConcept C178790620 @default.
• W2759333228 hasConcept C184651966 @default.
• W2759333228 hasConcept C185592680 @default.
• W2759333228 hasConcept C188027245 @default.
• W2759333228 hasConcept C2775998212 @default.
• W2759333228 hasConcept C2779448499 @default.
• W2759333228 hasConcept C2779679103 @default.
• W2759333228 hasConcept C2780378348 @default.
• W2759333228 hasConcept C2781144210 @default.
• W2759333228 hasConcept C41008148 @default.
• W2759333228 hasConcept C48333953 @default.
• W2759333228 hasConcept C521977710 @default.
• W2759333228 hasConcept C6557445 @default.
• W2759333228 hasConcept C76155785 @default.
• W2759333228 hasConcept C86803240 @default.
• W2759333228 hasConcept C94412978 @default.
• W2759333228 hasConceptScore W2759333228C124681953 @default.
• W2759333228 hasConceptScore W2759333228C137776501 @default.
• W2759333228 hasConceptScore W2759333228C155574463 @default.
• W2759333228 hasConceptScore W2759333228C178790620 @default.
• W2759333228 hasConceptScore W2759333228C184651966 @default.
• W2759333228 hasConceptScore W2759333228C185592680 @default.
• W2759333228 hasConceptScore W2759333228C188027245 @default.
• W2759333228 hasConceptScore W2759333228C2775998212 @default.
• W2759333228 hasConceptScore W2759333228C2779448499 @default.
• W2759333228 hasConceptScore W2759333228C2779679103 @default.
• W2759333228 hasConceptScore W2759333228C2780378348 @default.
• W2759333228 hasConceptScore W2759333228C2781144210 @default.
• W2759333228 hasConceptScore W2759333228C41008148 @default.
• W2759333228 hasConceptScore W2759333228C48333953 @default.
• W2759333228 hasConceptScore W2759333228C521977710 @default.
• W2759333228 hasConceptScore W2759333228C6557445 @default.
• W2759333228 hasConceptScore W2759333228C76155785 @default.
• W2759333228 hasConceptScore W2759333228C86803240 @default.

• next