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- W2760061505 abstract "Reaction of isopropylthiobenzene with n -BuLi, and subsequently with iron carbonyl and iodine gave a dimeric ortho -isopropylthiobenzoyl iron derivative[( o - i PrS)C 6 H 4 COFe(CO) 2 I] 2 through two iodide bridges, while similar reaction of thioanisole only yielded mononuclear phenylthiomethyl iron complex C 6 H 5 SCH 2 Fe(CO) 3 I. These two complexes show significantly different reactivities upon treatment with various nucleophiles. For example, reaction of[( o - i PrS)C 6 H 4 COFe(CO) 2 I] 2 with sodium 2-pyridinethiolate (PySNa) give mononuclear complex ( o - i PrS)C 6 H 4 COFe(CO) 2 (SPy), while reaction of C 6 H 5 SCH 2 Fe(CO) 3 I with PySNa results in the decomposition of the starting material. On the other hand, reaction of C 6 H 5 SCH 2 Fe(CO) 3 I with PPh 3 give complex C 6 H 5 SCH 2 Fe(CO) 2 (PPh 3 )I, but no characterizable product is obtained from the similar reaction of[( o - i PrS)C 6 H 4 COFe(CO) 2 I] 2 . All these newly synthesized compounds have been characterized by physico-chemical and spectroscopic methods, and their structures were unambiguously determined by X-ray crystallography.CCDC: 1545834, 1 ; 1545835, 2A ; 1545836, 3 ; 1545837, 4 ." @default.
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- W2760061505 date "2017-09-10" @default.
- W2760061505 modified "2023-09-23" @default.
- W2760061505 title "Synthesis and Reactivity of ortho -Isopropylthiobenzoyl and Phenylthiomethyl Iron Derivatives" @default.
- W2760061505 doi "https://doi.org/10.11862/cjic.2017.192" @default.
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