FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2760250892> ?p ?o ?g. }

• W2760250892 endingPage "35739" @default.
• W2760250892 startingPage "35729" @default.
• W2760250892 abstract "Magnesium batteries offer an opportunity to use naturally abundant Mg and achieve large volumetric capacities reaching over four times that of conventional Li-based intercalation anodes. High volumetric capacity is enabled by the use of a Mg metal anode in which charge is stored via electrodeposition and stripping processes, however, electrolytes that support efficient Mg electrodeposition and stripping are few and are often prepared from highly reactive compounds. One interesting electrolyte solution that supports Mg deposition and stripping without the use of highly reactive reagents is the magnesium aluminum chloride complex (MACC) electrolyte. The MACC exhibits high Coulombic efficiencies and low deposition overpotentials following an electrolytic conditioning protocol that stabilizes species necessary for such behavior. Here, we discuss the effect of the MgCl2 and AlCl3 concentrations on the deposition overpotential, current density, and the conditioning process. Higher concentrations of MACC exhibit enhanced Mg electrodeposition current density and much faster conditioning. An increase in the salt concentrations causes a shift in the complex equilibria involving both cations. The conditioning process is strongly dependent on the concentration suggesting that the electrolyte is activated through a change in speciation of electrolyte complexes and is not simply due to the annihilation of electrolyte impurities. Additionally, the presence of the [Mg2(μ-Cl)3·6THF]+ in the electrolyte solution is again confirmed through careful analysis of experimental Raman spectra coupled with simulation and direct observation of the complex in sonic spray ionization mass spectrometry. Importantly, we suggest that the ∼210 cm–1 mode commonly observed in the Raman spectra of many Mg electrolytes is indicative of the C3v symmetric [Mg2(μ-Cl)3·6THF]+. The 210 cm–1 mode is present in many electrolytes containing MgCl2, so its assignment is of broad interest to the Mg electrolyte community." @default.
• W2760250892 created "2017-10-06" @default.
• W2760250892 creator A5008793845 @default.
• W2760250892 creator A5021345935 @default.
• W2760250892 creator A5049886971 @default.
• W2760250892 creator A5059937910 @default.
• W2760250892 creator A5064941367 @default.
• W2760250892 date "2017-10-05" @default.
• W2760250892 modified "2023-10-18" @default.
• W2760250892 title "Effect of Concentration on the Electrochemistry and Speciation of the Magnesium Aluminum Chloride Complex Electrolyte Solution" @default.
• W2760250892 cites W1639753480 @default.
• W2760250892 cites W1662374196 @default.
• W2760250892 cites W1939645166 @default.
• W2760250892 cites W1946200942 @default.
• W2760250892 cites W1969760407 @default.
• W2760250892 cites W1973035169 @default.
• W2760250892 cites W1973567075 @default.
• W2760250892 cites W1982468602 @default.
• W2760250892 cites W1989727271 @default.
• W2760250892 cites W1994391661 @default.
• W2760250892 cites W1996290978 @default.
• W2760250892 cites W1996870438 @default.
• W2760250892 cites W1997151511 @default.
• W2760250892 cites W2019732897 @default.
• W2760250892 cites W2023881002 @default.
• W2760250892 cites W2024197554 @default.
• W2760250892 cites W2038525444 @default.
• W2760250892 cites W2051406801 @default.
• W2760250892 cites W2057938083 @default.
• W2760250892 cites W2062451512 @default.
• W2760250892 cites W2064391824 @default.
• W2760250892 cites W2067435855 @default.
• W2760250892 cites W2077804634 @default.
• W2760250892 cites W2079112095 @default.
• W2760250892 cites W2081235448 @default.
• W2760250892 cites W2092122420 @default.
• W2760250892 cites W2097410446 @default.
• W2760250892 cites W2122497506 @default.
• W2760250892 cites W2127084638 @default.
• W2760250892 cites W2131210504 @default.
• W2760250892 cites W2147006635 @default.
• W2760250892 cites W2171908409 @default.
• W2760250892 cites W2174654599 @default.
• W2760250892 cites W2188391249 @default.
• W2760250892 cites W2322272570 @default.
• W2760250892 cites W2322358865 @default.
• W2760250892 cites W2330240583 @default.
• W2760250892 cites W2337386572 @default.
• W2760250892 cites W2412810613 @default.
• W2760250892 cites W2460434900 @default.
• W2760250892 cites W2528381075 @default.
• W2760250892 cites W2545797655 @default.
• W2760250892 cites W2569249227 @default.
• W2760250892 cites W2591886272 @default.
• W2760250892 cites W2605909511 @default.
• W2760250892 cites W2952815280 @default.
• W2760250892 cites W3125394546 @default.
• W2760250892 cites W4243076992 @default.
• W2760250892 doi "https://doi.org/10.1021/acsami.7b08088" @default.
• W2760250892 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28933814" @default.
• W2760250892 hasPublicationYear "2017" @default.
• W2760250892 type Work @default.
• W2760250892 sameAs 2760250892 @default.
• W2760250892 citedByCount "55" @default.
• W2760250892 countsByYear W27602508922018 @default.
• W2760250892 countsByYear W27602508922019 @default.
• W2760250892 countsByYear W27602508922020 @default.
• W2760250892 countsByYear W27602508922021 @default.
• W2760250892 countsByYear W27602508922022 @default.
• W2760250892 countsByYear W27602508922023 @default.
• W2760250892 crossrefType "journal-article" @default.
• W2760250892 hasAuthorship W2760250892A5008793845 @default.
• W2760250892 hasAuthorship W2760250892A5021345935 @default.
• W2760250892 hasAuthorship W2760250892A5049886971 @default.
• W2760250892 hasAuthorship W2760250892A5059937910 @default.
• W2760250892 hasAuthorship W2760250892A5064941367 @default.
• W2760250892 hasConcept C130349721 @default.
• W2760250892 hasConcept C147789679 @default.
• W2760250892 hasConcept C159985019 @default.
• W2760250892 hasConcept C17525397 @default.
• W2760250892 hasConcept C179104552 @default.
• W2760250892 hasConcept C185592680 @default.
• W2760250892 hasConcept C186460083 @default.
• W2760250892 hasConcept C191897082 @default.
• W2760250892 hasConcept C192562407 @default.
• W2760250892 hasConcept C2778695967 @default.
• W2760250892 hasConcept C41952129 @default.
• W2760250892 hasConcept C52859227 @default.
• W2760250892 hasConcept C543218039 @default.
• W2760250892 hasConcept C68801617 @default.
• W2760250892 hasConcept C89395315 @default.
• W2760250892 hasConceptScore W2760250892C130349721 @default.
• W2760250892 hasConceptScore W2760250892C147789679 @default.
• W2760250892 hasConceptScore W2760250892C159985019 @default.
• W2760250892 hasConceptScore W2760250892C17525397 @default.
• W2760250892 hasConceptScore W2760250892C179104552 @default.
• W2760250892 hasConceptScore W2760250892C185592680 @default.
• W2760250892 hasConceptScore W2760250892C186460083 @default.

• next