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- W2760643996 abstract "A simple benzothiazole fluorescent chemosensor was developed for the fast sequential detection of Cu2 + and biothiols through modulating the excited-state intramolecular proton transfer (ESIPT) process. The compound 1 exhibits highly selective and sensitive fluorescence “on-off” recognition to Cu2 + with a 1:1 binding stoichiometry by ESIPT hinder. The in situ generated 1-Cu2 + complex can serve as an “on-off” fluorescent probe for high selectivity toward biothiols via Cu2 + displacement approach, which exerts ESIPT recovery. It is worth pointing out that the 1-Cu2 + complex shows faster for cysteins (within 1 min) than other biothiols such as homocysteine (25 min) and glutathione (25 min). Moreover, the compound 1 displays 160 nm Stoke-shift for reversibly monitoring Cu2 + and biothiols. In addition, the probe is successfully used for fluorescent cellular imaging. This strategy via modulation the ESIPT state has been used for determination of Cu2 + and Cys with satisfactory results, which further demonstrates its value of practical applications." @default.
- W2760643996 created "2017-10-06" @default.
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- W2760643996 date "2018-02-01" @default.
- W2760643996 modified "2023-10-15" @default.
- W2760643996 title "A simple fluorescent probe for the fast sequential detection of copper and biothiols based on a benzothiazole derivative" @default.
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- W2760643996 doi "https://doi.org/10.1016/j.saa.2017.09.069" @default.
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