Matches in SemOpenAlex for { <https://semopenalex.org/work/W2760708312> ?p ?o ?g. }
- W2760708312 endingPage "1990" @default.
- W2760708312 startingPage "1978" @default.
- W2760708312 abstract "The P–H functionalized Al/P‐based frustrated Lewis pair (FLP) Mes(H)P–C[Al{CH(SiMe 3 ) 2 } 2 ]=C(H)– t Bu ( 3 ) has the typical functionality of FLPs with Lewis acidic and basic centers in a single molecule and is able to transfer the P bound H atom to activated substrates. Nevertheless, 3 reacted with NH 3 only by adduct formation with the N atom coordinated to Al ( 5 ). The relatively low basicity of the P atom prevented the formation of a hydrogen bridge between P and Al. Similarly, benzil and 3 afforded a simple adduct ( 6 ) with only one C=O group bonded to P and Al. The second C=O group and the P–H moiety were unaffected. 6 has two stereogenic centers, and the resulting diastereomers were identified by crystal structure determinations. Migration of the P bound H atom was only observed for substrates containing basic N atoms. Nitriles gave heterocyclic iminophosphine adducts ( 7 ) in which the N–H groups were coordinated to the Al atoms. An isocyanate and two isothiocyanates afforded adducts via Al– X and P–C bond formation ( X = O, S), and phosphaurea derivatives ( 8a to 8c ) resulted from H shift to the exocyclic N atoms. A carbodiimide reacted with 3 by the formation of a phosphaguanidine ( 8d ) with the imine N atom coordinated to Al. The latter reactions proceed under mild conditions and represent formally the hydrophosphination of unsaturated substrates." @default.
- W2760708312 created "2017-10-06" @default.
- W2760708312 creator A5007878945 @default.
- W2760708312 creator A5013505085 @default.
- W2760708312 creator A5020249994 @default.
- W2760708312 creator A5032754495 @default.
- W2760708312 creator A5080433352 @default.
- W2760708312 creator A5088823361 @default.
- W2760708312 date "2017-10-16" @default.
- W2760708312 modified "2023-09-27" @default.
- W2760708312 title "Reactivity of a P–H Functionalized Al/P‐Based Frustrated Lewis Pair – Hydrophosphination versus Classic Adduct Formation" @default.
- W2760708312 cites W1588703153 @default.
- W2760708312 cites W1678846486 @default.
- W2760708312 cites W1713507700 @default.
- W2760708312 cites W1721211297 @default.
- W2760708312 cites W1856371759 @default.
- W2760708312 cites W1897198241 @default.
- W2760708312 cites W1963815550 @default.
- W2760708312 cites W1969502105 @default.
- W2760708312 cites W1974604648 @default.
- W2760708312 cites W1975311723 @default.
- W2760708312 cites W1975822790 @default.
- W2760708312 cites W1979143876 @default.
- W2760708312 cites W1980980798 @default.
- W2760708312 cites W1995272574 @default.
- W2760708312 cites W2001670536 @default.
- W2760708312 cites W2003613806 @default.
- W2760708312 cites W2025688917 @default.
- W2760708312 cites W2031504182 @default.
- W2760708312 cites W2038613461 @default.
- W2760708312 cites W2045173752 @default.
- W2760708312 cites W2047700223 @default.
- W2760708312 cites W2053844754 @default.
- W2760708312 cites W2063947632 @default.
- W2760708312 cites W2064897209 @default.
- W2760708312 cites W2068370512 @default.
- W2760708312 cites W2072480931 @default.
- W2760708312 cites W2074236245 @default.
- W2760708312 cites W2077354155 @default.
- W2760708312 cites W2082690721 @default.
- W2760708312 cites W2095903872 @default.
- W2760708312 cites W2100605529 @default.
- W2760708312 cites W2103304695 @default.
- W2760708312 cites W2119590660 @default.
- W2760708312 cites W2126455297 @default.
- W2760708312 cites W2126875005 @default.
- W2760708312 cites W2128643931 @default.
- W2760708312 cites W2131350133 @default.
- W2760708312 cites W2132173090 @default.
- W2760708312 cites W2136030002 @default.
- W2760708312 cites W2141754854 @default.
- W2760708312 cites W2143453620 @default.
- W2760708312 cites W2144279151 @default.
- W2760708312 cites W2149644813 @default.
- W2760708312 cites W2149805816 @default.
- W2760708312 cites W2150759589 @default.
- W2760708312 cites W2154010969 @default.
- W2760708312 cites W2161432570 @default.
- W2760708312 cites W2172011268 @default.
- W2760708312 cites W2234744023 @default.
- W2760708312 cites W2257475802 @default.
- W2760708312 cites W2257492138 @default.
- W2760708312 cites W2283486803 @default.
- W2760708312 cites W2298623631 @default.
- W2760708312 cites W2312455579 @default.
- W2760708312 cites W2319863753 @default.
- W2760708312 cites W2320290797 @default.
- W2760708312 cites W2322761555 @default.
- W2760708312 cites W2323573277 @default.
- W2760708312 cites W2323621950 @default.
- W2760708312 cites W2323685802 @default.
- W2760708312 cites W2324565240 @default.
- W2760708312 cites W2325797793 @default.
- W2760708312 cites W2327303995 @default.
- W2760708312 cites W2331304583 @default.
- W2760708312 cites W2333525916 @default.
- W2760708312 cites W2395064857 @default.
- W2760708312 cites W2415607014 @default.
- W2760708312 cites W2417336535 @default.
- W2760708312 cites W2419557021 @default.
- W2760708312 cites W2422338264 @default.
- W2760708312 cites W2464096748 @default.
- W2760708312 cites W2481773560 @default.
- W2760708312 cites W2499365402 @default.
- W2760708312 cites W2519555257 @default.
- W2760708312 cites W2526817456 @default.
- W2760708312 cites W2550673104 @default.
- W2760708312 cites W2585274539 @default.
- W2760708312 cites W2594029827 @default.
- W2760708312 cites W2738704045 @default.
- W2760708312 cites W2738896003 @default.
- W2760708312 cites W2739225777 @default.
- W2760708312 cites W2949604361 @default.
- W2760708312 cites W2949856398 @default.
- W2760708312 cites W2951876334 @default.
- W2760708312 cites W4230949004 @default.
- W2760708312 doi "https://doi.org/10.1002/zaac.201700340" @default.
- W2760708312 hasPublicationYear "2017" @default.