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• W2760769987 endingPage "5651" @default.
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• W2760769987 abstract "The synthesis of TiO2 was studied in an original hydrothermal process that uses triethanolamine titanium complex Ti(TeoaH)2 as a Ti precursor and triethanolamine (TeoaH3) as a shape controller to obtain bipyramidal anatase nanoparticles. Backed-up by experimental evidence, i.e., time profiles for Ti(IV) species concentrations together with crystal shape and particle size distributions measured by dynamic light scattering and electron microscopy, a mathematical model was built. The model includes chemical reactions responsible for TiO2 generation in solution and the subsequent anatase nucleation and crystal growth. The oriented attachment mechanism was adopted to explain the build-up of crystals with equilibrium anatase structure (Wulff structure) and time-varying shape factor. This complex mathematical model was solved writing and validating an in-house software using the Matlab (Natick, MA, USA) environment. The process was simulated for a batch time of 50 h, and the results, in terms of main species concentration and crystal size distributions, are in rather good agreement with the experimental measurements." @default.
• W2760769987 created "2017-10-06" @default.
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• W2760769987 date "2017-10-06" @default.
• W2760769987 modified "2023-10-16" @default.
• W2760769987 title "A New Model for Nano-TiO₂ Crystal Birth and Growth in Hydrothermal Treatment Using an Oriented Attachment Approach" @default.
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• W2760769987 doi "https://doi.org/10.1021/acs.cgd.7b00302" @default.
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