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- W2760872772 abstract "The reaction of alkenes (allyl alcohol, styrene and C6 alkenes) with formaldehyde was efficiently performed by using Rh precatalysts formed <em>in situ</em> by the addition of triphenylphosphine (PPh<sub>3</sub>), 1,2-bis(diphenylphosphino)ethane (dppe) or 1,1,1-tris(diphenylphosphinomethyl) ethane (triphos) to the complex Rh(acac)(CO)<sub>2</sub> at 130ºC in 1,4-dioxane, yielding their corresponding aldehydes; the best catalytic system was Rh(acac)(CO)<sub>2</sub>/2dppe, which generates the cationic complex [Rh(k<sup>2</sup>-P,P-dppe)<sub>2</sub>]<sup>+</sup>. However, the reaction of phenylacetylene with formaldehyde under the same reaction conditions generated styrene, which was found to be the product of transfer hydrogenation from formaldehyde." @default.
- W2760872772 created "2017-10-20" @default.
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- W2760872772 date "2017-10-12" @default.
- W2760872772 modified "2023-09-27" @default.
- W2760872772 title "Reactions of alkenes and alkynes with formaldehyde catalyzed by rhodium systems containing phosphine ligands" @default.
- W2760872772 doi "https://doi.org/10.29356/jmcs.v61i2.259" @default.
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