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- W2761127002 abstract "Zeolitic imidazolate framework-8 shares the same topology with sodalite zeolite but consists of Zn nodes bridged by imidazolate linkers to form a neutral open-framework structure. ZIF-8 has been recognized as a unique molecular sieving material with a flexible framework enabling interesting “gate-opening” functionality. Controlling the crystal size and shape is crucial for regulating the structural flexibilities and mass transport properties. The present study demonstrates that an aqueous-system-enabled spray-drying process enables the shape engineering of ZIF-8 with a hollow polycrystalline structure. It is notable that our synthesis route produces an amorphous zinc complex compound, which possesses a continuous random network partially with crystalline fillers, after spray drying followed by an amorphous-to-crystal transition via activation treatment using polar organic solvents. The size of primary ZIF-8 crystals consisting of secondary polycrystals depends on the kind of the organic solvent. The macro-/microscopic structures of hollow polycrystalline ZIF-8 significantly structurally enhanced the adsorption capacity and uptake rate. The large-scale, rapid production and enhanced adsorption performances make this continuous method a very promising candidate for industrial applications and shaping of MOF." @default.
- W2761127002 created "2017-10-20" @default.
- W2761127002 creator A5003268809 @default.
- W2761127002 creator A5049384937 @default.
- W2761127002 date "2017-10-05" @default.
- W2761127002 modified "2023-10-16" @default.
- W2761127002 title "Aqueous-System-Enabled Spray-Drying Technique for the Synthesis of Hollow Polycrystalline ZIF-8 MOF Particles" @default.
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- W2761127002 doi "https://doi.org/10.1021/acsomega.7b01325" @default.
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