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• W2761197813 endingPage "38930" @default.
• W2761197813 startingPage "38919" @default.
• W2761197813 abstract "Carbon dioxide capture and transformation are of great importance to make cuts in greenhouse gas emissions. Nanometal-organic frameworks (NMOFs) could serve as ideal fillers for polymer membranes owing to their structural diversity and regulable microenvironment of the nanocage. Herein, a bifunctional, robust, and chemically cross-linked NMOF-based membrane was successfully constructed by the postsynthetic polymerization of imidazolium-based ionic liquid (IL)-decorated UiO-66 type nanoparticles (NPs) and the isocyanate-terminated polyurethane oligomer under mild conditions. The IL-modified MOF-polymer membranes exhibit a highly selective adsorption for CO2 over N2 and CH4. In addition, the obtained membrane can also be a highly active heterogeneous catalyst for CO2 transformation by cycloaddition with epoxide under an ambient pressure." @default.
• W2761197813 created "2017-10-20" @default.
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• W2761197813 date "2017-10-25" @default.
• W2761197813 modified "2023-10-18" @default.
• W2761197813 title "Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO₂ Separation and Conversion" @default.
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• W2761197813 doi "https://doi.org/10.1021/acsami.7b12697" @default.
• W2761197813 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29027785" @default.
• W2761197813 hasPublicationYear "2017" @default.
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