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• W2761332425 startingPage "5347" @default.
• W2761332425 abstract "Adsorption of ionic liquids (ILs) onto activated carbons (ACs) has been proposed as a thermodynamically and kinetically suitable treatment to remove and/or recover ILs from liquid phase. This work evaluates the potential of AC adsorption in a fixed-bed column to remove ILs from aqueous streams. Different operating conditions were evaluated including AC particle size (0.10 mm–0.75 mm) and surface liquid velocity (1.4–2.0 m h−1). ILs of different nature were used to assess the influence of cation family (imidazolium- and pyridinium-based) and anion structure (modifying the IL polarity) in the adsorption performance. The adsorption of ILs by ACs in the fixed-bed column was described through the breakthrough curves obtained from experimental tests, which were modelled by the Yoon-Nelson equation. Adsorption capacity (qs), length of the mass transfer zone (HMTZ) and fractional bed utilization (FBU) were estimated from the breakthrough curves. The Yoon-Nelson model describes reasonably well the breakthrough curves, providing a valuable tool design for adsorption. Optimum performance was achieved for hydrophobic ILs at AC particle size between (0.10–0.25) mm and a surface liquid velocity of 1.4 m h−1. The results of fixed-bed adsorption of ILs were comparable to the obtained with commercial AC for dyes and emergent pollutants." @default.
• W2761332425 created "2017-10-20" @default.
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• W2761332425 date "2017-12-01" @default.
• W2761332425 modified "2023-10-11" @default.
• W2761332425 title "Fixed-bed adsorption of ionic liquids onto activated carbon from aqueous phase" @default.
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• W2761332425 doi "https://doi.org/10.1016/j.jece.2017.10.014" @default.
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