FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2761561036> ?p ?o ?g. }

• W2761561036 abstract "Most substances can crystallise into two or more different crystal lattices called polymorphs. Despite this, there are no systems in which we can quantitatively predict the probability of one competing polymorph forming instead of the other. We address this problem using large scale (hundreds of events) studies of the competing nucleation of the alpha and gamma polymorphs of glycine. In situ Raman spectroscopy is used to identify the polymorph of each crystal. We find that the nucleation kinetics of the two polymorphs is very different. Nucleation of the alpha polymorph starts off slowly but accelerates, while nucleation of the gamma polymorph starts off fast but then slows. We exploit this difference to increase the purity with which we obtain the gamma polymorph by a factor of ten. The statistics of the nucleation of crystals is analogous to that of human mortality, and using a result from medical statistics, we show that conventional nucleation data can say nothing about what, if any, are the correlations between competing nucleation processes. Thus we can show that with data of our form it is impossible to disentangle the competing nucleation processes. We also find that the growth rate and the shape of a crystal depend on it when nucleated. This is new evidence that nucleation and growth are linked." @default.
• W2761561036 created "2017-10-20" @default.
• W2761561036 creator A5015126074 @default.
• W2761561036 creator A5043385061 @default.
• W2761561036 creator A5075247944 @default.
• W2761561036 creator A5090873283 @default.
• W2761561036 date "2017-10-13" @default.
• W2761561036 modified "2023-09-27" @default.
• W2761561036 title "Controlling the crystal polymorph by exploiting the time dependence of nucleation rates" @default.
• W2761561036 cites W1580142972 @default.
• W2761561036 cites W1968324829 @default.
• W2761561036 cites W1973411595 @default.
• W2761561036 cites W1978163443 @default.
• W2761561036 cites W1981130475 @default.
• W2761561036 cites W1990293713 @default.
• W2761561036 cites W1994566480 @default.
• W2761561036 cites W1997085117 @default.
• W2761561036 cites W2000462982 @default.
• W2761561036 cites W2003117413 @default.
• W2761561036 cites W2009225010 @default.
• W2761561036 cites W2024385229 @default.
• W2761561036 cites W2026600174 @default.
• W2761561036 cites W2027988283 @default.
• W2761561036 cites W2028103928 @default.
• W2761561036 cites W2034429339 @default.
• W2761561036 cites W2049065191 @default.
• W2761561036 cites W2054594212 @default.
• W2761561036 cites W2057168369 @default.
• W2761561036 cites W2058341100 @default.
• W2761561036 cites W2062979984 @default.
• W2761561036 cites W2066070146 @default.
• W2761561036 cites W2068096554 @default.
• W2761561036 cites W2069726142 @default.
• W2761561036 cites W2071401898 @default.
• W2761561036 cites W2077635859 @default.
• W2761561036 cites W2078189107 @default.
• W2761561036 cites W2123362440 @default.
• W2761561036 cites W2131980091 @default.
• W2761561036 cites W2138905359 @default.
• W2761561036 cites W2143367459 @default.
• W2761561036 cites W2194227006 @default.
• W2761561036 cites W2280714565 @default.
• W2761561036 cites W2316088916 @default.
• W2761561036 cites W2316975220 @default.
• W2761561036 cites W2320471387 @default.
• W2761561036 cites W2324583072 @default.
• W2761561036 cites W2327130112 @default.
• W2761561036 cites W2328692532 @default.
• W2761561036 cites W2332595175 @default.
• W2761561036 cites W2333955089 @default.
• W2761561036 cites W2334826174 @default.
• W2761561036 cites W2418778595 @default.
• W2761561036 cites W2518313499 @default.
• W2761561036 cites W4245738600 @default.
• W2761561036 doi "https://doi.org/10.1063/1.4993566" @default.
• W2761561036 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29031253" @default.
• W2761561036 hasPublicationYear "2017" @default.
• W2761561036 type Work @default.
• W2761561036 sameAs 2761561036 @default.
• W2761561036 citedByCount "5" @default.
• W2761561036 countsByYear W27615610362018 @default.
• W2761561036 countsByYear W27615610362019 @default.
• W2761561036 countsByYear W27615610362020 @default.
• W2761561036 countsByYear W27615610362021 @default.
• W2761561036 crossrefType "journal-article" @default.
• W2761561036 hasAuthorship W2761561036A5015126074 @default.
• W2761561036 hasAuthorship W2761561036A5043385061 @default.
• W2761561036 hasAuthorship W2761561036A5075247944 @default.
• W2761561036 hasAuthorship W2761561036A5090873283 @default.
• W2761561036 hasBestOaLocation W27615610362 @default.
• W2761561036 hasConcept C121332964 @default.
• W2761561036 hasConcept C159467904 @default.
• W2761561036 hasConcept C185592680 @default.
• W2761561036 hasConcept C192562407 @default.
• W2761561036 hasConcept C199360897 @default.
• W2761561036 hasConcept C26456737 @default.
• W2761561036 hasConcept C2781285689 @default.
• W2761561036 hasConcept C41008148 @default.
• W2761561036 hasConcept C61048295 @default.
• W2761561036 hasConcept C8010536 @default.
• W2761561036 hasConcept C97355855 @default.
• W2761561036 hasConceptScore W2761561036C121332964 @default.
• W2761561036 hasConceptScore W2761561036C159467904 @default.
• W2761561036 hasConceptScore W2761561036C185592680 @default.
• W2761561036 hasConceptScore W2761561036C192562407 @default.
• W2761561036 hasConceptScore W2761561036C199360897 @default.
• W2761561036 hasConceptScore W2761561036C26456737 @default.
• W2761561036 hasConceptScore W2761561036C2781285689 @default.
• W2761561036 hasConceptScore W2761561036C41008148 @default.
• W2761561036 hasConceptScore W2761561036C61048295 @default.
• W2761561036 hasConceptScore W2761561036C8010536 @default.
• W2761561036 hasConceptScore W2761561036C97355855 @default.
• W2761561036 hasFunder F4320334627 @default.
• W2761561036 hasIssue "14" @default.
• W2761561036 hasLocation W27615610361 @default.
• W2761561036 hasLocation W27615610362 @default.
• W2761561036 hasLocation W27615610363 @default.
• W2761561036 hasLocation W27615610364 @default.
• W2761561036 hasLocation W27615610365 @default.
• W2761561036 hasOpenAccess W2761561036 @default.

• next