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- W2761718265 abstract "Abstract Peroxosolvates of 2‐aminonicotinic acid ( I ) and lidocaine N ‐oxide ( II ) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single‐crystal X‐ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I . An unusual cross‐like pentameric cluster was observed in the structure of II . The topology of the (H 2 O 2 ) 12 assembly was never observed for small‐molecule clusters. In I and II new double and triple cross‐orientational disorders of H 2 O 2 were found. Cluster II is the first example of a peroxosolvate crystal structure containing H 2 O 2 molecules with a homoleptic hydrogen peroxide environment. In II , a hydrogen bond between an H 2 O 2 molecule and a peptide group ‐CONH⋅⋅⋅O 2 H 2 was observed for the first time." @default.
- W2761718265 created "2017-10-20" @default.
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- W2761718265 date "2017-10-19" @default.
- W2761718265 modified "2023-10-14" @default.
- W2761718265 title "Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures" @default.
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- W2761718265 doi "https://doi.org/10.1002/anie.201709699" @default.
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