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• W2762207776 endingPage "4100" @default.
• W2762207776 startingPage "4090" @default.
• W2762207776 abstract "Influence of the two different anion structures viz. bis(fluorosulfonyl)imide (FSI−) and bis(trifluoromethanesulfonyl) imide (TFSI−), on the thermophysical, dielectric and electrochemical properties of ZrO2-nanoparticle tethered pyrrolidinium based nanoscale hybrid ionic fluids (NHIFs) was investigated. Thermal and mechanical properties of NHIFs were found to depend strongly upon the structure of anions and TFSI− comprising NHIF showed better thermal and mechanical stability then its FSI− analogue. Temperature dependent electrical conductivity, dielectric and electrochemical properties of different NHIFs were studied. FSI-NHIF displayed higher ionic conductivity, associated with faster structural relaxation dynamics. At all the measured temperature, FSI-NHIF displayed superior electrochemical cycling performance than its TFSI-equivalent. While, electrochemical cell with TFSI-NHIF showed 81% capacitance retentivity after 5000 charge/discharge cycles, FSI-NHIF cell was found to retain >90% of its initial specific capacitance value after the same. Results obtained from the study optimize the applicability of pyrrolidinium based hybrid ionic fluids as electrolytes in secondary energy storage devices." @default.
• W2762207776 created "2017-10-20" @default.
• W2762207776 creator A5031513647 @default.
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• W2762207776 date "2018-02-01" @default.
• W2762207776 modified "2023-10-15" @default.
• W2762207776 title "Influence of anion structure on thermal, mechanical, dielectric and electrochemical properties of ZrO 2 nanoparticle-pyrrolidinium ionic liquid hybrid electrolytes for the application in energy storage devices" @default.
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• W2762207776 doi "https://doi.org/10.1016/j.ijhydene.2017.09.023" @default.
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