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- W2762556867 abstract "Abstract The germanides RE 3 Pt 4 Ge 6 ( RE =Y, Pr, Nd, Sm, Gd–Dy) have been synthesized by arc-melting of the elements followed by inductive annealing to improve the crystallinity and allow for structural order. The compounds have been studied by powder X-ray diffraction; additionally the structure of Y 3 Pt 4 Ge 6 has been refined from single-crystal X-ray diffractometer data. It exhibits a (3+1)D modulated structure, indicating isotypism with Ce 3 Pt 4 Ge 6 . The crystal structure can be described as an intergrowth between YIrGe 2 - and CaBe 2 Ge 2 -type slabs along [100]. Temperature-dependent magnetic susceptibility measurements showed Pauli paramagnetism for Y 3 Pt 4 Ge 6 and Curie-Weiss paramagnetism for Pr 3 Pt 4 Ge 6 and Nd 3 Pt 4 Ge 6 . Sm 3 Pt 4 Ge 6 exhibits van Vleck paramagnetism, while antiferromagnetic ordering at T N =8.1(1) K and T N =11.0(1) K is observed for Gd 3 Pt 4 Ge 6 and Tb 3 Pt 4 Ge 6 , respectively." @default.
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- W2762556867 date "2017-10-11" @default.
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- W2762556867 title "Magnetic properties of the germanides <i>RE</i> <sub>3</sub>Pt<sub>4</sub>Ge<sub>6</sub> (<i>RE</i>=Y, Pr, Nd, Sm, Gd–Dy)" @default.
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- W2762556867 doi "https://doi.org/10.1515/znb-2017-0123" @default.
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