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- W2762826178 abstract "Abstract Two piano-stool type mono-iron complexes featuring Cp*N (Cp*N = η5-C5Me4(CH2)2NMe2) ligand were synthesized by one-electron oxidation of the corresponding dimer precursors. Furthermore, carbonyl ligand was smoothly replaced by MeCN molecule under illumination. Interestingly, the protonation of the amino group in the side chain led to dissociation of the nitrogen atom from the iron center. Reversibly, deprotonation by a weak base recovered the coordination capacity of the nitrogen atom. These results exhibit the function of the nitrogen atom in the second coordination sphere of some metalloenzymes as a potential proton relay site." @default.
- W2762826178 created "2017-10-20" @default.
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- W2762826178 date "2017-12-01" @default.
- W2762826178 modified "2023-10-16" @default.
- W2762826178 title "Proton mediated switching of the coordination states of the tethered N-atom in iron complex featuring a pendent amine functionalized Cp* ligand" @default.
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- W2762826178 doi "https://doi.org/10.1016/j.inoche.2017.10.011" @default.
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