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- W2763139736 abstract "Core–shell magnetic Fe3O4@C nanospheres functionalized with active chemical groups were synthesized via a one-step template-free solvothermal process and employed to remove hexavalent chromium (Cr(VI)) in aqueous media. The structure of Fe3O4@C nanoparticles could be effectively adjusted by the concentration of precursor. The Fe3O4 core possessed a high magnetism for the convenient separation of Fe3O4@C from aqueous solution, and high porosity and abundant functional groups (−OH, −COOH, and C═C) of carbon layer contributed to a superior performance on Cr(VI) removal. Therein, Cr(VI) ions could be efficiently adsorbed into the carbon layer and reduced to trivalent chromium (Cr(III)) mainly by C═C, and the resulting Cr(III) were chelated by the −COOH group. Noteworthy, the carbon layer thickness, pore size, and amount of chemical groups significantly increased with the increase of Fe3O4@C particle size resulting in a rising removal efficiency on Cr(VI). This study provides a promising approach for removing Cr(VI) and may have a huge application potential." @default.
- W2763139736 created "2017-10-20" @default.
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- W2763139736 date "2017-10-17" @default.
- W2763139736 modified "2023-10-17" @default.
- W2763139736 title "Functionalized Fe<sub>3</sub>O<sub>4</sub>@C Nanospheres with Adjustable Structure for Efficient Hexavalent Chromium Removal" @default.
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- W2763139736 doi "https://doi.org/10.1021/acssuschemeng.7b02983" @default.
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