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- W2763385890 abstract "Abstract Optical memory effect plays a critical role in energy-saving coefficient of electrochromic devices (ECDs). Due to the finite electron-blocking capacity of ions electrolyte layer and the weak interfacial energy between the ions electrolyte layer and electrochromic layers, typically five-layer inorganic all-solid-state ECDs generally suffer from poor optical memory. A seven-layer inorganic ECD with significantly improved optical memory is designed by means of the embedment of Ta 2 O 5 layers between ions conductive layer and electrochromic layers. Compared with the typical five-layer ECD-1 (ITO/NiO x /LiNbO 3 /WO 3 /ITO), the seven-layer ECD-2 with the structure of ITO/NiO x /Ta 2 O 5 /LiNbO 3 /Ta 2 O 5 /WO 3 /ITO presents much less leakage current, larger optical modulation and higher coloration efficiency during electrochemical cycling. The further analyses reveal that the embedded Ta 2 O 5 layers greatly increase the energy barrier between NiO x , WO 3 and LiNbO 3 , imposing restrictions on the transfer kinetics of electrons contributing to the leakage current and enlarging the threshold potential available to ECD-2, which gives rise to a high coloration efficiency up to 98.0 cm 2 C −1 . Furthermore, the seven-layer ECD-2 maintains a stable optical modulation of approximately 52.5% for over 10,000 cycles, even though there is a compromise in response characteristic due to the Li + -ion trapping in electrochromic layers, which provides a further insight into the electrochromic degradation of inorganic all-solid-state complementary ECDs." @default.
- W2763385890 created "2017-10-20" @default.
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- W2763385890 date "2018-01-01" @default.
- W2763385890 modified "2023-10-16" @default.
- W2763385890 title "Charge-transfer kinetics and cyclic properties of inorganic all-solid-state electrochromic device with remarkably improved optical memory" @default.
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- W2763385890 doi "https://doi.org/10.1016/j.solmat.2017.09.012" @default.
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