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- W2763485105 abstract "Abstract A novel peptide–peptide ligation strategy is introduced that has the potential to provide peptide libraries of linearly or branched coupled fragments and will be suited to introduce simultaneous protein modifications at different ligation sites. Ligation is assisted by templating peptide nucleic acid (PNA) strands, and therefore, ligation specificity is solely encoded by the PNA sequence. PNA templating, in general, allows for various kinds of covalent ligation reactions. As a proof of principle, a native chemical ligation strategy was elaborated. This PNA‐templated ligation includes easy on‐resin procedures to couple linkers and PNA to the respective peptides, and a traceless photocleavage of the linker/PNA oligomer after the ligation step. A 4,5‐dimethoxy‐2‐nitrobenzaldehyde‐based linker that allowed the photocleavable linkage of two bio‐oligomers was developed." @default.
- W2763485105 created "2017-10-20" @default.
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- W2763485105 date "2017-11-02" @default.
- W2763485105 modified "2023-10-09" @default.
- W2763485105 title "Native Chemical Ligation Directed by Photocleavable Peptide Nucleic Acid (PNA) Templates" @default.
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- W2763485105 doi "https://doi.org/10.1002/cbic.201700487" @default.
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