Matches in SemOpenAlex for { <https://semopenalex.org/work/W2763889725> ?p ?o ?g. }
- W2763889725 endingPage "37738" @default.
- W2763889725 startingPage "37731" @default.
- W2763889725 abstract "Lithium-sulfur battery represents a promising class of energy storage technology owing to its high theoretical energy density and low cost. However, the insulating nature, shuttling of soluble polysulfides and volumetric expansion of sulfur electrodes seriously give rise to the rapid capacity fading and low utilization. In this work, these issues are significantly alleviated by both physically and chemically restricting sulfur species in fluorinated porous triazine-based frameworks (FCTF-S). One-step trimerization of perfluorinated aromatic nitrile monomers with elemental sulfur allows the simultaneous formation of fluorinated triazine-based frameworks, covalent attachment of sulfur and its homogeneous distribution within the pores. The incorporation of electronegative fluorine in frameworks provides a strong anchoring effect to suppress the dissolution and accelerate the conversion of polysulfides. Together with covalent chemical binding and physical nanopore-confinement effects, the FCTF-S demonstrates superior electrochemical performances, as compared to those of the sulfur-rich covalent triazine-based framework without fluorine (CTF-S) and porous carbon delivering only physical confinement. Our approach demonstrates the potential of regulating lithium-sulfur battery performances at a molecular scale promoted by the porous organic polymers with a flexible design." @default.
- W2763889725 created "2017-10-20" @default.
- W2763889725 creator A5012585051 @default.
- W2763889725 creator A5016827442 @default.
- W2763889725 creator A5021830722 @default.
- W2763889725 creator A5029568025 @default.
- W2763889725 creator A5039762605 @default.
- W2763889725 creator A5051515822 @default.
- W2763889725 date "2017-10-18" @default.
- W2763889725 modified "2023-10-16" @default.
- W2763889725 title "Fluorinated, Sulfur-Rich, Covalent Triazine Frameworks for Enhanced Confinement of Polysulfides in Lithium–Sulfur Batteries" @default.
- W2763889725 cites W1826084136 @default.
- W2763889725 cites W1876006411 @default.
- W2763889725 cites W1953303465 @default.
- W2763889725 cites W1974454071 @default.
- W2763889725 cites W1975507538 @default.
- W2763889725 cites W1976453341 @default.
- W2763889725 cites W1978674631 @default.
- W2763889725 cites W1987722945 @default.
- W2763889725 cites W1987891017 @default.
- W2763889725 cites W1998010272 @default.
- W2763889725 cites W2001762523 @default.
- W2763889725 cites W2009860903 @default.
- W2763889725 cites W2014285671 @default.
- W2763889725 cites W2029366295 @default.
- W2763889725 cites W2058208815 @default.
- W2763889725 cites W2066822904 @default.
- W2763889725 cites W2066943025 @default.
- W2763889725 cites W2071253878 @default.
- W2763889725 cites W2073008431 @default.
- W2763889725 cites W2080185665 @default.
- W2763889725 cites W2104015519 @default.
- W2763889725 cites W2104551659 @default.
- W2763889725 cites W2117006210 @default.
- W2763889725 cites W2124516633 @default.
- W2763889725 cites W2125658152 @default.
- W2763889725 cites W2139377809 @default.
- W2763889725 cites W2144257491 @default.
- W2763889725 cites W2151207643 @default.
- W2763889725 cites W2191355709 @default.
- W2763889725 cites W2226018809 @default.
- W2763889725 cites W2227043478 @default.
- W2763889725 cites W2261365795 @default.
- W2763889725 cites W2272188882 @default.
- W2763889725 cites W2284687880 @default.
- W2763889725 cites W2289100720 @default.
- W2763889725 cites W2304901112 @default.
- W2763889725 cites W2314803279 @default.
- W2763889725 cites W2333033211 @default.
- W2763889725 cites W2342744270 @default.
- W2763889725 cites W2476116270 @default.
- W2763889725 cites W2482083820 @default.
- W2763889725 cites W2506728426 @default.
- W2763889725 cites W2507911448 @default.
- W2763889725 cites W2508563296 @default.
- W2763889725 cites W2513287540 @default.
- W2763889725 cites W2518579027 @default.
- W2763889725 cites W2520979964 @default.
- W2763889725 cites W2522247135 @default.
- W2763889725 cites W2556198110 @default.
- W2763889725 cites W2562010062 @default.
- W2763889725 cites W2564707016 @default.
- W2763889725 cites W2592400953 @default.
- W2763889725 cites W2612686288 @default.
- W2763889725 cites W606815474 @default.
- W2763889725 cites W2579847911 @default.
- W2763889725 doi "https://doi.org/10.1021/acsami.7b10991" @default.
- W2763889725 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28990391" @default.
- W2763889725 hasPublicationYear "2017" @default.
- W2763889725 type Work @default.
- W2763889725 sameAs 2763889725 @default.
- W2763889725 citedByCount "146" @default.
- W2763889725 countsByYear W27638897252018 @default.
- W2763889725 countsByYear W27638897252019 @default.
- W2763889725 countsByYear W27638897252020 @default.
- W2763889725 countsByYear W27638897252021 @default.
- W2763889725 countsByYear W27638897252022 @default.
- W2763889725 countsByYear W27638897252023 @default.
- W2763889725 crossrefType "journal-article" @default.
- W2763889725 hasAuthorship W2763889725A5012585051 @default.
- W2763889725 hasAuthorship W2763889725A5016827442 @default.
- W2763889725 hasAuthorship W2763889725A5021830722 @default.
- W2763889725 hasAuthorship W2763889725A5029568025 @default.
- W2763889725 hasAuthorship W2763889725A5039762605 @default.
- W2763889725 hasAuthorship W2763889725A5051515822 @default.
- W2763889725 hasConcept C121332964 @default.
- W2763889725 hasConcept C127413603 @default.
- W2763889725 hasConcept C147789679 @default.
- W2763889725 hasConcept C159985019 @default.
- W2763889725 hasConcept C163258240 @default.
- W2763889725 hasConcept C17525397 @default.
- W2763889725 hasConcept C178790620 @default.
- W2763889725 hasConcept C179104552 @default.
- W2763889725 hasConcept C180577832 @default.
- W2763889725 hasConcept C185592680 @default.
- W2763889725 hasConcept C188027245 @default.
- W2763889725 hasConcept C191897082 @default.
- W2763889725 hasConcept C192562407 @default.