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• W2764002200 abstract "We observe temperature-dependent phase changes in a precursor of europium-doped titania (p-Eu:TiO2) that is prepared via precipitation and is laser-heated to temperatures between 473 K and 1246 K within sub-second heating durations. The phase changes are characterized using X-ray diffraction and site-selective photoluminescence spectroscopy. We find that upon heating, the initially amorphous p-Eu:TiO2 first transforms into the anatase phase and then into a mixed anatase/rutile phase. These phase transformations change the local environment of the dopant Eu3+ ions resulting in modifications to the Eu3+ ions spectroscopic properties, with the modifications occurring for calcination temperatures above approximately 573 K following sub-second durations. These results demonstrate the temperature sensing ability of p-Eu:TiO2 nanoparticles for use in sub-second heating events. Moreover, at 573 K this temperature is lower than other host materials that we have evaluated (i.e., La2O3, ZrO2 and Y2O3)." @default.
• W2764002200 created "2017-10-20" @default.
• W2764002200 creator A5036999004 @default.
• W2764002200 creator A5058884328 @default.
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• W2764002200 date "2018-02-01" @default.
• W2764002200 modified "2023-10-18" @default.
• W2764002200 title "Structural and spectroscopic characterization of irreversible phase changes in rapidly heated precursors of europium-doped titania nanoparticles" @default.
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• W2764002200 doi "https://doi.org/10.1016/j.jssc.2017.10.001" @default.
• W2764002200 hasPublicationYear "2018" @default.
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