FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2764148270> ?p ?o ?g. }

• W2764148270 endingPage "36848" @default.
• W2764148270 startingPage "36837" @default.
• W2764148270 abstract "Synthesis of nanostructured transition metal sulfides is of particular interest in providing new methods to control their porosity and improve their surface area because those sulfides hold promising applications in high-energy density devices. Significant challenges remain currently to prepare metal sulfides having three-dimensional (3-D) continuous mesoporous structures, known to be critical for increasing their active surface sites and enhancing ion transport. We herein present a facile solid-phase sulfurization method to synthesize 3-D continuous mesoporous CoS2, NiS2, and their binary sulfides in a two-step nanocasting using bicontinuous KIT-6 as hard templates. The solid-phase sulfurization taking place at 400 °C yields mesoporous sulfides with highly crystalline frameworks and a stoichiometric ratio of metal-to-sulfur, 1:2 (mol), within 30 min. Elemental sulfur as an inexpensive sulfur source can be directly used for the solid-phase sulfurization of mesoporous oxides of Co3O4, NiO, and their binary oxides. This facile synthetic method is highly efficient to prepare mesoporous sulfides in the gram-scale production at a very low cost. Mesoporous sulfides are demonstrated to be superior electrode materials for pseudo-supercapacitors, given their high surface area and accessible bicontinuous mesopores, the suitable crystalline sizes, and the enhanced ion transport capability. The use of binary mesoporous sulfides presents interesting synergetic effect where the doping of metal ions can significantly enhance the capacitive performance of single-component sulfides. The binary sulfides of mNi0.32Co0.68S2 show a specific capacitance up to 1698 F g-1 at a current density of 2 A g-1. The supercapacitor device of mNi0.32Co0.68S2 has a high energy density of 37 Wh kg-1 at a power density of 800 W kg-1. We believe that the reported solid-phase synthesis offers a universal method toward the conversion of mesoporous oxides materials into various useful and functional forms for energy conversion and storage applications." @default.
• W2764148270 created "2017-10-20" @default.
• W2764148270 creator A5006250732 @default.
• W2764148270 creator A5019358573 @default.
• W2764148270 creator A5043424489 @default.
• W2764148270 creator A5078758903 @default.
• W2764148270 creator A5082155967 @default.
• W2764148270 date "2017-10-16" @default.
• W2764148270 modified "2023-10-12" @default.
• W2764148270 title "Synthesis of Mesoporous CoS₂ and Ni<i>_x</i>Co_1–<i>x</i>S₂ with Superior Supercapacitive Performance Using a Facile Solid-Phase Sulfurization" @default.
• W2764148270 cites W1168521798 @default.
• W2764148270 cites W1180893007 @default.
• W2764148270 cites W1267917630 @default.
• W2764148270 cites W1802379727 @default.
• W2764148270 cites W1899952564 @default.
• W2764148270 cites W1912475885 @default.
• W2764148270 cites W1958947896 @default.
• W2764148270 cites W1972484444 @default.
• W2764148270 cites W1982383223 @default.
• W2764148270 cites W1985502096 @default.
• W2764148270 cites W1986725651 @default.
• W2764148270 cites W1988664917 @default.
• W2764148270 cites W1992425965 @default.
• W2764148270 cites W1993145847 @default.
• W2764148270 cites W1993274927 @default.
• W2764148270 cites W1999564939 @default.
• W2764148270 cites W2003092971 @default.
• W2764148270 cites W2006268894 @default.
• W2764148270 cites W2006318126 @default.
• W2764148270 cites W2006553433 @default.
• W2764148270 cites W2017305999 @default.
• W2764148270 cites W2018864861 @default.
• W2764148270 cites W2032638239 @default.
• W2764148270 cites W2047685836 @default.
• W2764148270 cites W2056607023 @default.
• W2764148270 cites W2057232367 @default.
• W2764148270 cites W2058318619 @default.
• W2764148270 cites W2062999495 @default.
• W2764148270 cites W2071393589 @default.
• W2764148270 cites W2071890521 @default.
• W2764148270 cites W2079493928 @default.
• W2764148270 cites W2088775325 @default.
• W2764148270 cites W2119591966 @default.
• W2764148270 cites W2123884652 @default.
• W2764148270 cites W2132905138 @default.
• W2764148270 cites W2136189070 @default.
• W2764148270 cites W2141457431 @default.
• W2764148270 cites W2156376762 @default.
• W2764148270 cites W2187594337 @default.
• W2764148270 cites W2297933183 @default.
• W2764148270 cites W2313702111 @default.
• W2764148270 cites W2319125198 @default.
• W2764148270 cites W2322881879 @default.
• W2764148270 cites W2330127009 @default.
• W2764148270 cites W2331222924 @default.
• W2764148270 cites W2332693356 @default.
• W2764148270 cites W2338864311 @default.
• W2764148270 cites W2344908403 @default.
• W2764148270 cites W2347135063 @default.
• W2764148270 cites W2419553187 @default.
• W2764148270 cites W2461658204 @default.
• W2764148270 cites W2488018267 @default.
• W2764148270 cites W2490330714 @default.
• W2764148270 cites W2512341042 @default.
• W2764148270 cites W2556723530 @default.
• W2764148270 cites W2564879251 @default.
• W2764148270 cites W2606232383 @default.
• W2764148270 cites W2607018122 @default.
• W2764148270 cites W2613241133 @default.
• W2764148270 cites W2889615184 @default.
• W2764148270 cites W2950072654 @default.
• W2764148270 cites W4238007676 @default.
• W2764148270 cites W4253331426 @default.
• W2764148270 doi "https://doi.org/10.1021/acsami.7b11453" @default.
• W2764148270 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28980805" @default.
• W2764148270 hasPublicationYear "2017" @default.
• W2764148270 type Work @default.
• W2764148270 sameAs 2764148270 @default.
• W2764148270 citedByCount "60" @default.
• W2764148270 countsByYear W27641482702018 @default.
• W2764148270 countsByYear W27641482702019 @default.
• W2764148270 countsByYear W27641482702020 @default.
• W2764148270 countsByYear W27641482702021 @default.
• W2764148270 countsByYear W27641482702022 @default.
• W2764148270 countsByYear W27641482702023 @default.
• W2764148270 crossrefType "journal-article" @default.
• W2764148270 hasAuthorship W2764148270A5006250732 @default.
• W2764148270 hasAuthorship W2764148270A5019358573 @default.
• W2764148270 hasAuthorship W2764148270A5043424489 @default.
• W2764148270 hasAuthorship W2764148270A5078758903 @default.
• W2764148270 hasAuthorship W2764148270A5082155967 @default.
• W2764148270 hasConcept C106773901 @default.
• W2764148270 hasConcept C127413603 @default.
• W2764148270 hasConcept C147789679 @default.
• W2764148270 hasConcept C150581940 @default.
• W2764148270 hasConcept C161790260 @default.
• W2764148270 hasConcept C171250308 @default.
• W2764148270 hasConcept C17525397 @default.

• next