FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W276443629> ?p ?o ?g. }

• W276443629 endingPage "153" @default.
• W276443629 startingPage "129" @default.
• W276443629 abstract "The content and nature of soil organic matter, and especially of its humic acid (HA) fraction, is ascertained to be a major factor for pesticide adsorption in soil. Organic amendment of soil is known to affect the amount and chemical properties of native soil HAs. This effect is thus expected to modify the quantitative and mechanistic aspects of pesticide adsorption to soil HAs. The binding mechanisms and adsorption isotherms of the pesticides alachlor [2-chloro-2′,6′-diethyl-N-(methoxymethyl)acetanilide], imazethapyr [(RS)-5-ethyl2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinic acid], rimsulfuron [N-[(4,6-dimethoxypyrimidine-2-yl)carbamoyl]-3-(ethylsulfonyl)-2-pyridine sulfonamide], triallate (S-2,3,3-trichloroallyl diisopropylthiocarbamate), and chlordane (1,2,4,5,6,7,8,8-octachlor-2,3,3a,4,7,7a,-hexahydro-4,7-methano-indene) to HAs from two sewage sludges and a pig slurry and from a number of nonamended and amended soils have been studied in two distinct experiments. Binding mechanisms were investigated on HA pesticide interactions by use of chemical and spectroscopic methods including Fourier-transform infrared (FTIR), fluorescence and electron spin resonance (ESR). Adsorption isotherms of pesticides to HAs were obtained by using a batch equilibrium method coupled with high-pressure liquid or gas chromatographic analyses. Spectroscopic data suggest that moderately water-soluble, polar pesticides such as alachlor, imazethapyr and rimsulfuron are mainly adsorbed to HAs by multiple binding mechanisms, including H-bonding and ionic and charge-transfer processes, whereas the low water-soluble, nonpolar triallate and chlordane preferentially bind to Has by hydrophobic bonding. The highly aliphatic, low humified HAs from organic amendments tend to bind pesticides by hydrophobic bonding, whereas the well humified soil HAs would prefer chemical binding forms. In general, alachlor and triallate exhibit linear isotherms, imazethapyr nonlinear Freundlich isotherms of the C-type, and rimsulfuron and chlordane Langmuir-type isotherms in their adsorption to HAs. The extent of adsorption of the various pesticides onto HAs follows the order: chlordane〉 triallate 》 rimsulfuron 》 imazethapyr 〉 alachlor. The adsorption capacity of the various HAs for the different pesticides is variable and related to the composition and structural and functional properties of the HA. In conclusion, organic amendment of soil has been shown to affect the magnitude and modify the mechanisms of pesticide adsorption to soil HAs." @default.
• W276443629 created "2016-06-24" @default.
• W276443629 creator A5040213590 @default.
• W276443629 creator A5044186278 @default.
• W276443629 creator A5047521889 @default.
• W276443629 creator A5053958200 @default.
• W276443629 creator A5087798383 @default.
• W276443629 creator A5088948736 @default.
• W276443629 date "2015-11-02" @default.
• W276443629 modified "2023-10-14" @default.
• W276443629 title "Adsorption of Pesticides by Humic Acids from Organic Amendments and Soils" @default.
• W276443629 cites W1190080693 @default.
• W276443629 cites W1540568962 @default.
• W276443629 cites W1979332776 @default.
• W276443629 cites W1987088772 @default.
• W276443629 cites W1997563978 @default.
• W276443629 cites W2002098317 @default.
• W276443629 cites W2047138163 @default.
• W276443629 cites W2050406995 @default.
• W276443629 cites W2060673571 @default.
• W276443629 cites W2063699941 @default.
• W276443629 cites W2075059851 @default.
• W276443629 cites W2090812836 @default.
• W276443629 cites W2143438291 @default.
• W276443629 cites W2480428849 @default.
• W276443629 cites W2781514354 @default.
• W276443629 cites W2946438681 @default.
• W276443629 cites W71684619 @default.
• W276443629 cites W85918912 @default.
• W276443629 doi "https://doi.org/10.2136/2001.humicsubstances.c8" @default.
• W276443629 hasPublicationYear "2015" @default.
• W276443629 type Work @default.
• W276443629 sameAs 276443629 @default.
• W276443629 citedByCount "10" @default.
• W276443629 countsByYear W2764436292016 @default.
• W276443629 countsByYear W2764436292017 @default.
• W276443629 countsByYear W2764436292019 @default.
• W276443629 countsByYear W2764436292021 @default.
• W276443629 countsByYear W2764436292022 @default.
• W276443629 countsByYear W2764436292023 @default.
• W276443629 crossrefType "book-chapter" @default.
• W276443629 hasAuthorship W276443629A5040213590 @default.
• W276443629 hasAuthorship W276443629A5044186278 @default.
• W276443629 hasAuthorship W276443629A5047521889 @default.
• W276443629 hasAuthorship W276443629A5053958200 @default.
• W276443629 hasAuthorship W276443629A5087798383 @default.
• W276443629 hasAuthorship W276443629A5088948736 @default.
• W276443629 hasConcept C107872376 @default.
• W276443629 hasConcept C150394285 @default.
• W276443629 hasConcept C159390177 @default.
• W276443629 hasConcept C159750122 @default.
• W276443629 hasConcept C161176658 @default.
• W276443629 hasConcept C178790620 @default.
• W276443629 hasConcept C185592680 @default.
• W276443629 hasConcept C2778659605 @default.
• W276443629 hasConcept C2779595939 @default.
• W276443629 hasConcept C2780359760 @default.
• W276443629 hasConcept C2780560099 @default.
• W276443629 hasConcept C2780965034 @default.
• W276443629 hasConcept C39432304 @default.
• W276443629 hasConcept C48743137 @default.
• W276443629 hasConcept C6557445 @default.
• W276443629 hasConcept C86803240 @default.
• W276443629 hasConceptScore W276443629C107872376 @default.
• W276443629 hasConceptScore W276443629C150394285 @default.
• W276443629 hasConceptScore W276443629C159390177 @default.
• W276443629 hasConceptScore W276443629C159750122 @default.
• W276443629 hasConceptScore W276443629C161176658 @default.
• W276443629 hasConceptScore W276443629C178790620 @default.
• W276443629 hasConceptScore W276443629C185592680 @default.
• W276443629 hasConceptScore W276443629C2778659605 @default.
• W276443629 hasConceptScore W276443629C2779595939 @default.
• W276443629 hasConceptScore W276443629C2780359760 @default.
• W276443629 hasConceptScore W276443629C2780560099 @default.
• W276443629 hasConceptScore W276443629C2780965034 @default.
• W276443629 hasConceptScore W276443629C39432304 @default.
• W276443629 hasConceptScore W276443629C48743137 @default.
• W276443629 hasConceptScore W276443629C6557445 @default.
• W276443629 hasConceptScore W276443629C86803240 @default.
• W276443629 hasLocation W2764436291 @default.
• W276443629 hasOpenAccess W276443629 @default.
• W276443629 hasPrimaryLocation W2764436291 @default.
• W276443629 hasRelatedWork W1560432281 @default.
• W276443629 hasRelatedWork W2012921226 @default.
• W276443629 hasRelatedWork W2285455483 @default.
• W276443629 hasRelatedWork W2327476094 @default.
• W276443629 hasRelatedWork W2479433623 @default.
• W276443629 hasRelatedWork W2497952138 @default.
• W276443629 hasRelatedWork W2506227312 @default.
• W276443629 hasRelatedWork W2762172992 @default.
• W276443629 hasRelatedWork W2795503608 @default.
• W276443629 hasRelatedWork W2947669891 @default.
• W276443629 isParatext "false" @default.
• W276443629 isRetracted "false" @default.
• W276443629 magId "276443629" @default.
• W276443629 workType "book-chapter" @default.