FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2765129054> ?p ?o ?g. }

• W2765129054 endingPage "392" @default.
• W2765129054 startingPage "382" @default.
• W2765129054 abstract "We have determined breakdown curves for a range of multiply charged benzylpyridinium-substituted porphyrin cations by collision induced dissociation measurements (CID) as mediated by resonant pulsed radio-frequency (rf) excitation in a helium-filled linear ion trap. Measurements were compared with the predictions of DFT calculations. We find a linear correlation between experimental fragmentation thresholds (in instrumental units of “normalized collision energy”) and theoretical dissociation energies, suggesting that these species can be used as calibrants to gauge the fragmentation energetics of closely related systems. We have confirmed this by also studying the fragmentation thresholds of metalloporphyrin-based ions – including multiply negatively charged metalloporphyrin oligomers. Unfortunately, the slope of the linear correlation obtained for benzylpyridinium-substituted porphyrin multications differs significantly from that obtained by us for a set of smaller, singly charged substituted benzylpyridines put forward as “thermometer” ions in previous work. Multiplying the threshold energies in an ad hoc fashion by the ion charge basically reconciles both calibration curves. We conclude that one should use caution when applying small, singly charged benzylpyridines as calibrants to gauge the CID of large, multiply charged ions in ion-trap mass spectrometers." @default.
• W2765129054 created "2017-11-10" @default.
• W2765129054 creator A5004498912 @default.
• W2765129054 creator A5035175627 @default.
• W2765129054 creator A5052144587 @default.
• W2765129054 creator A5062552492 @default.
• W2765129054 creator A5068783204 @default.
• W2765129054 creator A5084714835 @default.
• W2765129054 creator A5086991154 @default.
• W2765129054 date "2017-10-30" @default.
• W2765129054 modified "2023-10-17" @default.
• W2765129054 title "Collision Induced Dissociation of Benzylpyridinium-Substituted Porphyrins: Towards a Thermometer Scale for Multiply Charged Ions?" @default.
• W2765129054 cites W1974135531 @default.
• W2765129054 cites W1988348748 @default.
• W2765129054 cites W1993996846 @default.
• W2765129054 cites W1994103130 @default.
• W2765129054 cites W2002904554 @default.
• W2765129054 cites W2009283470 @default.
• W2765129054 cites W2011028578 @default.
• W2765129054 cites W2011207959 @default.
• W2765129054 cites W2017844253 @default.
• W2765129054 cites W2018309838 @default.
• W2765129054 cites W2020430110 @default.
• W2765129054 cites W2031405983 @default.
• W2765129054 cites W2052364984 @default.
• W2765129054 cites W2058100905 @default.
• W2765129054 cites W2058193939 @default.
• W2765129054 cites W2059679927 @default.
• W2765129054 cites W2060287301 @default.
• W2765129054 cites W2067603378 @default.
• W2765129054 cites W2069435842 @default.
• W2765129054 cites W2071373500 @default.
• W2765129054 cites W2072550255 @default.
• W2765129054 cites W2079202862 @default.
• W2765129054 cites W2081598183 @default.
• W2765129054 cites W2093252464 @default.
• W2765129054 cites W2102026659 @default.
• W2765129054 cites W2122765656 @default.
• W2765129054 cites W2135385298 @default.
• W2765129054 cites W2136174819 @default.
• W2765129054 cites W2144339524 @default.
• W2765129054 cites W2146783781 @default.
• W2765129054 cites W2152142256 @default.
• W2765129054 cites W2159410970 @default.
• W2765129054 cites W2162263095 @default.
• W2765129054 cites W2163153896 @default.
• W2765129054 cites W2169662771 @default.
• W2765129054 cites W2170053458 @default.
• W2765129054 cites W2317667683 @default.
• W2765129054 cites W2530199279 @default.
• W2765129054 doi "https://doi.org/10.1007/s13361-017-1835-4" @default.
• W2765129054 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29086339" @default.
• W2765129054 hasPublicationYear "2017" @default.
• W2765129054 type Work @default.
• W2765129054 sameAs 2765129054 @default.
• W2765129054 citedByCount "5" @default.
• W2765129054 countsByYear W27651290542018 @default.
• W2765129054 countsByYear W27651290542019 @default.
• W2765129054 countsByYear W27651290542021 @default.
• W2765129054 crossrefType "journal-article" @default.
• W2765129054 hasAuthorship W2765129054A5004498912 @default.
• W2765129054 hasAuthorship W2765129054A5035175627 @default.
• W2765129054 hasAuthorship W2765129054A5052144587 @default.
• W2765129054 hasAuthorship W2765129054A5062552492 @default.
• W2765129054 hasAuthorship W2765129054A5068783204 @default.
• W2765129054 hasAuthorship W2765129054A5084714835 @default.
• W2765129054 hasAuthorship W2765129054A5086991154 @default.
• W2765129054 hasConcept C102931765 @default.
• W2765129054 hasConcept C106289968 @default.
• W2765129054 hasConcept C111919701 @default.
• W2765129054 hasConcept C113196181 @default.
• W2765129054 hasConcept C119128265 @default.
• W2765129054 hasConcept C121332964 @default.
• W2765129054 hasConcept C145148216 @default.
• W2765129054 hasConcept C147789679 @default.
• W2765129054 hasConcept C162356407 @default.
• W2765129054 hasConcept C176107965 @default.
• W2765129054 hasConcept C178790620 @default.
• W2765129054 hasConcept C184779094 @default.
• W2765129054 hasConcept C185592680 @default.
• W2765129054 hasConcept C191015642 @default.
• W2765129054 hasConcept C23531484 @default.
• W2765129054 hasConcept C2779480358 @default.
• W2765129054 hasConcept C27826464 @default.
• W2765129054 hasConcept C31827203 @default.
• W2765129054 hasConcept C41008148 @default.
• W2765129054 hasConcept C43617362 @default.
• W2765129054 hasConcept C62520636 @default.
• W2765129054 hasConcept C75473681 @default.
• W2765129054 hasConcept C83581075 @default.
• W2765129054 hasConceptScore W2765129054C102931765 @default.
• W2765129054 hasConceptScore W2765129054C106289968 @default.
• W2765129054 hasConceptScore W2765129054C111919701 @default.
• W2765129054 hasConceptScore W2765129054C113196181 @default.
• W2765129054 hasConceptScore W2765129054C119128265 @default.
• W2765129054 hasConceptScore W2765129054C121332964 @default.
• W2765129054 hasConceptScore W2765129054C145148216 @default.
• W2765129054 hasConceptScore W2765129054C147789679 @default.

• next