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- W2765152118 abstract "A synthetic strategy has been developed for the synthesis of 2,3-disubstituted-1,4-naphthoquinones. This synthetic protocol consists of metal-free tert-Butyl hydroperoxide (TBHP)-mediated oxidative benzoylation followed by Pd-catalyzed Suzuki-cross coupling reactions. Benzaldehyde, benzylalcohol and toluene were efficiently used as benzoyl radical source for the benzoylation of 1,4-naphthoquinones. By this protocol, a wide range of 1,4-naphthoquinones with different substitution patterns were efficiently prepared in a sequential way with good to excellent yields." @default.
- W2765152118 created "2017-11-10" @default.
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- W2765152118 date "2017-10-31" @default.
- W2765152118 modified "2023-09-26" @default.
- W2765152118 title "Synthesis of 2,3-Disubstituted 1,4-Naphthoquinones via Metal-Free C(sp2)-H Functionalization Followed by Suzuki Cross-Coupling Reactions" @default.
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- W2765152118 doi "https://doi.org/10.1002/slct.201702404" @default.
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