Matches in SemOpenAlex for { <https://semopenalex.org/work/W2765220120> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2765220120 endingPage "95" @default.
- W2765220120 startingPage "95" @default.
- W2765220120 abstract "A new protocol has been developed for the regioselective preparation of 2,5-disubstituted pyrroles. This approach is based on a stepwise iododesilylation and a subsequent coupling reaction, involving a 6-step pathway starting from the simplest pyrrole. A variety of 2,5-disubstituted pyrrole derivatives are accessible in moderate to good yields. In this study, the protection group for the pyrrole nitrogen is carefully chosen and N,N-dimethylaminosulfonyl is the final choice, which facilitates the subsequent double lithiation and makes the pyrrole moiety more stable. However, the attempted removal of this group fails under several different conditions. Instead, unexpected dimethylaminosulfonyl migration to the β-position of the pyrrole ring in the presence of tetrabutylammonium fluoride is observed." @default.
- W2765220120 created "2017-11-10" @default.
- W2765220120 creator A5024546548 @default.
- W2765220120 creator A5056496295 @default.
- W2765220120 creator A5077094881 @default.
- W2765220120 creator A5082020327 @default.
- W2765220120 date "2018-01-01" @default.
- W2765220120 modified "2023-09-23" @default.
- W2765220120 title "Regioselective Synthesis of 2,5-Disubstituted Pyrroles via Stepwise Iododesilylation and Coupling Reactions" @default.
- W2765220120 cites W1845068383 @default.
- W2765220120 cites W1971532874 @default.
- W2765220120 cites W1982718031 @default.
- W2765220120 cites W1996759091 @default.
- W2765220120 cites W1997596301 @default.
- W2765220120 cites W2005128805 @default.
- W2765220120 cites W2010877956 @default.
- W2765220120 cites W2029492232 @default.
- W2765220120 cites W2048278494 @default.
- W2765220120 cites W2081941020 @default.
- W2765220120 cites W2129399508 @default.
- W2765220120 cites W2141171959 @default.
- W2765220120 cites W2149385698 @default.
- W2765220120 cites W2159323776 @default.
- W2765220120 cites W2345172980 @default.
- W2765220120 cites W2362026012 @default.
- W2765220120 cites W2951103361 @default.
- W2765220120 cites W2951183090 @default.
- W2765220120 cites W2952701281 @default.
- W2765220120 cites W574396864 @default.
- W2765220120 doi "https://doi.org/10.1071/ch17341" @default.
- W2765220120 hasPublicationYear "2018" @default.
- W2765220120 type Work @default.
- W2765220120 sameAs 2765220120 @default.
- W2765220120 citedByCount "3" @default.
- W2765220120 countsByYear W27652201202020 @default.
- W2765220120 countsByYear W27652201202021 @default.
- W2765220120 crossrefType "journal-article" @default.
- W2765220120 hasAuthorship W2765220120A5024546548 @default.
- W2765220120 hasAuthorship W2765220120A5056496295 @default.
- W2765220120 hasAuthorship W2765220120A5077094881 @default.
- W2765220120 hasAuthorship W2765220120A5082020327 @default.
- W2765220120 hasConcept C155647269 @default.
- W2765220120 hasConcept C161790260 @default.
- W2765220120 hasConcept C178790620 @default.
- W2765220120 hasConcept C185592680 @default.
- W2765220120 hasConcept C191503008 @default.
- W2765220120 hasConcept C21951064 @default.
- W2765220120 hasConcept C2776568683 @default.
- W2765220120 hasConcept C2779400197 @default.
- W2765220120 hasConcept C2780378348 @default.
- W2765220120 hasConcept C48424934 @default.
- W2765220120 hasConcept C59759590 @default.
- W2765220120 hasConcept C65024703 @default.
- W2765220120 hasConcept C71240020 @default.
- W2765220120 hasConceptScore W2765220120C155647269 @default.
- W2765220120 hasConceptScore W2765220120C161790260 @default.
- W2765220120 hasConceptScore W2765220120C178790620 @default.
- W2765220120 hasConceptScore W2765220120C185592680 @default.
- W2765220120 hasConceptScore W2765220120C191503008 @default.
- W2765220120 hasConceptScore W2765220120C21951064 @default.
- W2765220120 hasConceptScore W2765220120C2776568683 @default.
- W2765220120 hasConceptScore W2765220120C2779400197 @default.
- W2765220120 hasConceptScore W2765220120C2780378348 @default.
- W2765220120 hasConceptScore W2765220120C48424934 @default.
- W2765220120 hasConceptScore W2765220120C59759590 @default.
- W2765220120 hasConceptScore W2765220120C65024703 @default.
- W2765220120 hasConceptScore W2765220120C71240020 @default.
- W2765220120 hasIssue "3" @default.
- W2765220120 hasLocation W27652201201 @default.
- W2765220120 hasOpenAccess W2765220120 @default.
- W2765220120 hasPrimaryLocation W27652201201 @default.
- W2765220120 hasRelatedWork W2011746025 @default.
- W2765220120 hasRelatedWork W2020513179 @default.
- W2765220120 hasRelatedWork W2083777916 @default.
- W2765220120 hasRelatedWork W2085754972 @default.
- W2765220120 hasRelatedWork W2166549092 @default.
- W2765220120 hasRelatedWork W2765220120 @default.
- W2765220120 hasRelatedWork W2917295577 @default.
- W2765220120 hasRelatedWork W2950772616 @default.
- W2765220120 hasRelatedWork W2952515297 @default.
- W2765220120 hasRelatedWork W3080854563 @default.
- W2765220120 hasVolume "71" @default.
- W2765220120 isParatext "false" @default.
- W2765220120 isRetracted "false" @default.
- W2765220120 magId "2765220120" @default.
- W2765220120 workType "article" @default.