Matches in SemOpenAlex for { <https://semopenalex.org/work/W2765285174> ?p ?o ?g. }
- W2765285174 endingPage "13929" @default.
- W2765285174 startingPage "13913" @default.
- W2765285174 abstract "We report the formation of new cyclic porphyrin tetrads 1 and 2, which were obtained from the reaction between dihydroxytin(IV) porphyrin and cis-dihydroxy-21-thiaporphyrin/21,23-dithiaporphyrin. The unique oxophilicity of tin(IV) porphyrin was the driving force for the formation of these tetrads. Moreover, these novel tetrads represent the first examples of cyclic porphyrins containing tin(IV) that are constructed exclusively on the basis of the “Sn–O” interaction without any other complementary, noncompetitive mode of interactions. The molecular structures of the cyclic tetrads have been investigated by matrix-assisted laser desorption ionization time-of-flight mass spectrometry, NMR spectroscopy, quantum-mechanical calculations, and, in one case, single-crystal X-ray crystallography. The X-ray structure revealed that the two cis-dihydroxy-N2S2 porphyrins were coordinated at the axial positions of two tin(IV) porphyrins, leading to the symmetric cyclic tetrad structure. The optical properties of tetrads were studied, and these compounds were stable under redox conditions. Preliminary photophysical studies carried out on the tetrads indicated efficient energy transfer from tin(IV) porphyrin to the thiaporphyrin unit, which highlights their potential applications in energy and electron transfer in the future." @default.
- W2765285174 created "2017-11-10" @default.
- W2765285174 creator A5002660612 @default.
- W2765285174 creator A5004936397 @default.
- W2765285174 creator A5010380253 @default.
- W2765285174 creator A5054362570 @default.
- W2765285174 creator A5057126575 @default.
- W2765285174 creator A5069083005 @default.
- W2765285174 creator A5077490088 @default.
- W2765285174 creator A5086568685 @default.
- W2765285174 date "2017-10-31" @default.
- W2765285174 modified "2023-10-16" @default.
- W2765285174 title "Construction of Novel Cyclic Tetrads by Axial Coordination of Thiaporphyrins to Tin(IV) Porphyrin" @default.
- W2765285174 cites W1966182479 @default.
- W2765285174 cites W1968725733 @default.
- W2765285174 cites W1969216081 @default.
- W2765285174 cites W1970160732 @default.
- W2765285174 cites W1971364684 @default.
- W2765285174 cites W1971618311 @default.
- W2765285174 cites W1973639010 @default.
- W2765285174 cites W1979544533 @default.
- W2765285174 cites W1981368803 @default.
- W2765285174 cites W1983077892 @default.
- W2765285174 cites W1990373858 @default.
- W2765285174 cites W1991951181 @default.
- W2765285174 cites W1992670591 @default.
- W2765285174 cites W1993861622 @default.
- W2765285174 cites W1994379204 @default.
- W2765285174 cites W1995176463 @default.
- W2765285174 cites W1996438208 @default.
- W2765285174 cites W2002215992 @default.
- W2765285174 cites W2004575088 @default.
- W2765285174 cites W2005190633 @default.
- W2765285174 cites W2006747103 @default.
- W2765285174 cites W2012746456 @default.
- W2765285174 cites W2013998048 @default.
- W2765285174 cites W2016948970 @default.
- W2765285174 cites W2017823980 @default.
- W2765285174 cites W2019136970 @default.
- W2765285174 cites W2020525863 @default.
- W2765285174 cites W2023586901 @default.
- W2765285174 cites W2026742872 @default.
- W2765285174 cites W2027742766 @default.
- W2765285174 cites W2028046413 @default.
- W2765285174 cites W2029269395 @default.
- W2765285174 cites W2033011823 @default.
- W2765285174 cites W2033121534 @default.
- W2765285174 cites W2034690089 @default.
- W2765285174 cites W2037211136 @default.
- W2765285174 cites W2038302333 @default.
- W2765285174 cites W2038392478 @default.
- W2765285174 cites W2038583967 @default.
- W2765285174 cites W2039293281 @default.
- W2765285174 cites W2043031553 @default.
- W2765285174 cites W2043932221 @default.
- W2765285174 cites W2044490585 @default.
- W2765285174 cites W2044591029 @default.
- W2765285174 cites W2044889958 @default.
- W2765285174 cites W2047825983 @default.
- W2765285174 cites W2051235803 @default.
- W2765285174 cites W2058848030 @default.
- W2765285174 cites W2063951847 @default.
- W2765285174 cites W2064398572 @default.
- W2765285174 cites W2067718414 @default.
- W2765285174 cites W2068617439 @default.
- W2765285174 cites W2069039897 @default.
- W2765285174 cites W2071221934 @default.
- W2765285174 cites W2072552245 @default.
- W2765285174 cites W2073224048 @default.
- W2765285174 cites W2077217276 @default.
- W2765285174 cites W2077432622 @default.
- W2765285174 cites W2083222334 @default.
- W2765285174 cites W2084464517 @default.
- W2765285174 cites W2089465204 @default.
- W2765285174 cites W2089610351 @default.
- W2765285174 cites W2091551537 @default.
- W2765285174 cites W2093157819 @default.
- W2765285174 cites W2095359109 @default.
- W2765285174 cites W2096075731 @default.
- W2765285174 cites W2104049240 @default.
- W2765285174 cites W2113878267 @default.
- W2765285174 cites W2115127485 @default.
- W2765285174 cites W2116548138 @default.
- W2765285174 cites W2119547517 @default.
- W2765285174 cites W2133426573 @default.
- W2765285174 cites W2143981217 @default.
- W2765285174 cites W2145408306 @default.
- W2765285174 cites W2147096372 @default.
- W2765285174 cites W2151211956 @default.
- W2765285174 cites W2156584402 @default.
- W2765285174 cites W2168726637 @default.
- W2765285174 cites W2950041467 @default.
- W2765285174 cites W2950332593 @default.
- W2765285174 cites W2952249577 @default.
- W2765285174 cites W2952446758 @default.
- W2765285174 cites W43860648 @default.
- W2765285174 doi "https://doi.org/10.1021/acs.inorgchem.7b01966" @default.
- W2765285174 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29087196" @default.