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- W2765332364 abstract "Stereoselective total syntheses of the four stereoisomeric forms of guaiacylglycerol 8-O-4'-coniferyl ether, viz., compounds 1, ent-1, 2, and ent-2, have been established. The key step involves an Evans/Seebach auxiliary-controlled and syn-selective aldol process followed, in the reaction sequences leading to the anti-compounds, by a Mitsunobu reaction involving a benzylic alcohol residue. The proangiogenic properties of the synthetic materials were evaluated in a human microvascular endothelial cell tubule formation assay, thus revealing that they are all active, with the 8S-configured compounds 1 and 2 being the most potent." @default.
- W2765332364 created "2017-11-10" @default.
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- W2765332364 date "2017-10-30" @default.
- W2765332364 modified "2023-10-14" @default.
- W2765332364 title "Developing Neolignans as Proangiogenic Agents: Stereoselective Total Syntheses and Preliminary Biological Evaluations of the Four Guaiacylglycerol 8-<i>O</i>-4′-Coniferyl Ethers" @default.
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- W2765332364 doi "https://doi.org/10.1021/acsomega.7b01459" @default.
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