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• W2765389023 endingPage "104" @default.
• W2765389023 startingPage "97" @default.
• W2765389023 abstract "μ-XANES is used to study the modifications in the alkali and alkaline-earth environments induced by the Na+/K+ ion-exchange process in various Na –silicate glasses. The results indicate that the ion-exchange process induces a shortening of the NaO, CaO and MgO bond distances. The contraction of the NaO, CaO and MgO coordination shell allows a better accommodation of the K+ cations in the glass network and thereby leads to partial relaxation of the stress developed by the Na+/K+ ion-exchange. Nevertheless, despite the stress relaxation process, the K+ environment in the ion-exchanged glass is not equivalent to the one in Na,K–silicate as-melted glasses. Hence, this study clearly shows that the ion swapping forced K+ cations to occupy smaller sites which are not achievable via the melt quench route for glasses with the same K amount." @default.
• W2765389023 created "2017-11-10" @default.
• W2765389023 creator A5013478126 @default.
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• W2765389023 date "2018-01-01" @default.
• W2765389023 modified "2023-10-16" @default.
• W2765389023 title "A XANES investigation of the network-modifier cations environment before and after the Na + /K + ion-exchange in silicate glasses" @default.
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• W2765389023 doi "https://doi.org/10.1016/j.jnoncrysol.2017.10.021" @default.
• W2765389023 hasPublicationYear "2018" @default.
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