FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2765431594> ?p ?o ?g. }

• W2765431594 endingPage "705" @default.
• W2765431594 startingPage "699" @default.
• W2765431594 abstract "Abstract We report the successful isolation and structural elucidation of two bimetallic doped [Co 2 @Ge 16 ] 4− clusters (α and β form), which were synthesized through the reaction of [{(ArN) 2 C t Bu}Co(η 6 ‐toluene)] (Ar=2,6‐diisopropylphenyl) and K 4 Ge 9 in ethylenediamine (en) solution and co‐crystallized together in [K(2,2,2‐crypt)] 4 [Co 2 @Ge 16 ] ⋅ en. The α‐[Co 2 @Ge 16 ] 4− isomer prefers a distinct D 2 h 3‐connected architecture, whereas the deltahedral isomeric β‐[Co 2 @Ge 16 ] 4− isomer adopts a quasi‐ C 2 h geometry and can be seen as coupling of two distorted arachno ‐[Co@Ge 10 ] units. Chemical bonding analyses indicate that the skeleton of the α isomer is mainly composed of localized bonds, whereas only multicenter bonding interactions govern the geometry of the β isomer, which was further found to exhibit a fluxional behavior. The coexistence of both isomers within one unit cell links the 3‐connected clusters with their deltahedral congeners, thus highlighting the structural and electronic flexibility of such discreet cluster systems." @default.
• W2765431594 created "2017-11-10" @default.
• W2765431594 creator A5028296024 @default.
• W2765431594 creator A5031810848 @default.
• W2765431594 creator A5041872966 @default.
• W2765431594 creator A5048528947 @default.
• W2765431594 creator A5058523056 @default.
• W2765431594 creator A5088100414 @default.
• W2765431594 date "2017-12-06" @default.
• W2765431594 modified "2023-10-12" @default.
• W2765431594 title "[Co ₂ @Ge ₁₆ ] ⁴⁻ : Localized versus Delocalized Bonding in Two Isomeric Intermetalloid Clusters" @default.
• W2765431594 cites W1964179887 @default.
• W2765431594 cites W1966140209 @default.
• W2765431594 cites W1970388917 @default.
• W2765431594 cites W1974544564 @default.
• W2765431594 cites W1975458269 @default.
• W2765431594 cites W1979830711 @default.
• W2765431594 cites W1980718745 @default.
• W2765431594 cites W1984301840 @default.
• W2765431594 cites W1985130646 @default.
• W2765431594 cites W1992428710 @default.
• W2765431594 cites W1992787868 @default.
• W2765431594 cites W1993671107 @default.
• W2765431594 cites W1995794402 @default.
• W2765431594 cites W2015553247 @default.
• W2765431594 cites W2018037569 @default.
• W2765431594 cites W2025856127 @default.
• W2765431594 cites W2030670815 @default.
• W2765431594 cites W2032854332 @default.
• W2765431594 cites W2041989756 @default.
• W2765431594 cites W2043001214 @default.
• W2765431594 cites W2048999452 @default.
• W2765431594 cites W2049048912 @default.
• W2765431594 cites W2053172718 @default.
• W2765431594 cites W2058717265 @default.
• W2765431594 cites W2064221444 @default.
• W2765431594 cites W2064659751 @default.
• W2765431594 cites W2067650379 @default.
• W2765431594 cites W2071802677 @default.
• W2765431594 cites W2072752013 @default.
• W2765431594 cites W2073868456 @default.
• W2765431594 cites W2074369805 @default.
• W2765431594 cites W2088965396 @default.
• W2765431594 cites W2090495380 @default.
• W2765431594 cites W2092630919 @default.
• W2765431594 cites W2093076921 @default.
• W2765431594 cites W2093988081 @default.
• W2765431594 cites W2099818711 @default.
• W2765431594 cites W2105313015 @default.
• W2765431594 cites W2113175363 @default.
• W2765431594 cites W2120500904 @default.
• W2765431594 cites W2125525619 @default.
• W2765431594 cites W2125985071 @default.
• W2765431594 cites W2131041733 @default.
• W2765431594 cites W2131350133 @default.
• W2765431594 cites W2144717230 @default.
• W2765431594 cites W2146606147 @default.
• W2765431594 cites W2147044568 @default.
• W2765431594 cites W2150098183 @default.
• W2765431594 cites W2156257697 @default.
• W2765431594 cites W2156663663 @default.
• W2765431594 cites W2165668972 @default.
• W2765431594 cites W2165818049 @default.
• W2765431594 cites W2168956898 @default.
• W2765431594 cites W2169390022 @default.
• W2765431594 cites W2170963985 @default.
• W2765431594 cites W2184268253 @default.
• W2765431594 cites W2261475701 @default.
• W2765431594 cites W2261542628 @default.
• W2765431594 cites W2270113252 @default.
• W2765431594 cites W2316328113 @default.
• W2765431594 cites W2326659941 @default.
• W2765431594 cites W2332378578 @default.
• W2765431594 cites W2335170026 @default.
• W2765431594 cites W2466299476 @default.
• W2765431594 cites W2470674679 @default.
• W2765431594 cites W2480162833 @default.
• W2765431594 cites W2502372942 @default.
• W2765431594 cites W2567364945 @default.
• W2765431594 cites W2586343059 @default.
• W2765431594 cites W2950769920 @default.
• W2765431594 cites W2951825196 @default.
• W2765431594 cites W2952748025 @default.
• W2765431594 cites W2952839491 @default.
• W2765431594 cites W4236210902 @default.
• W2765431594 cites W4237067492 @default.
• W2765431594 cites W4239006037 @default.
• W2765431594 cites W4246532583 @default.
• W2765431594 cites W4247364118 @default.
• W2765431594 cites W4247457517 @default.
• W2765431594 cites W4252159295 @default.
• W2765431594 cites W180436973 @default.
• W2765431594 doi "https://doi.org/10.1002/chem.201704444" @default.
• W2765431594 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29071743" @default.
• W2765431594 hasPublicationYear "2017" @default.
• W2765431594 type Work @default.
• W2765431594 sameAs 2765431594 @default.
• W2765431594 citedByCount "51" @default.

• next