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• W2765434567 abstract "A synthesis of allahabadolactone A is described employing diastereoselective Diels-Alder and selenocyclization reactions, starting from (R)-citronellal and propylene oxide. The Diels-Alder substrate is built up in an efficient manner by rhodium-catalyzed alkyne hydroboration and palladium-catalyzed coupling reactions of E-1,2-dichloroethene. It is observed that the Diels-Alder reaction only displays high diastereoselectivity when the diene bears an additional alkene substituent but not an alkyne substituent." @default.
• W2765434567 created "2017-11-10" @default.
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• W2765434567 date "2017-11-07" @default.
• W2765434567 modified "2023-09-27" @default.
• W2765434567 title "Synthesis of Allahabadolactone A" @default.
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• W2765434567 doi "https://doi.org/10.1021/acs.joc.7b02368" @default.
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