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- W2765463016 endingPage "16099" @default.
- W2765463016 startingPage "16096" @default.
- W2765463016 abstract "The first enantioselective total synthesis of the complex tricarbocyclic sesquiterpenoid periconianone A based on a postulated biogenesis is reported. Key elements of the synthetic route include the use of an isopropenyl group as a removable directing group for stereoselective synthesis, a sequence featuring a Rh-mediated O-H insertion/[3,3]-sigmatropic rearrangement and subsequent α-ketol rearrangement, and a late stage aldol reaction to furnish the complex cage-like framework." @default.
- W2765463016 created "2017-11-10" @default.
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- W2765463016 date "2017-11-02" @default.
- W2765463016 modified "2023-10-04" @default.
- W2765463016 title "Total Synthesis of the Sesquiterpenoid Periconianone A Based on a Postulated Biogenesis" @default.
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- W2765463016 doi "https://doi.org/10.1021/jacs.7b10053" @default.
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