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- W2765508718 abstract "Abstract We present a novel route for the quick and easy synthesis of a broad range of β‐lactams. The synthesis involves a [3+1] cyclization of amide dianions with diiodomethane. In contrast to the seminal work of Hirai et al. from 1979, the reaction proved to be a general and efficient approach towards azetidinones. The ease of the process was confirmed by DFT calculations and its power demonstrated by a diversity‐oriented synthesis of β‐lactams with four points of diversity determined by the choice of Ugi adducts as starting materials." @default.
- W2765508718 created "2017-11-10" @default.
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- W2765508718 date "2017-08-24" @default.
- W2765508718 modified "2023-10-12" @default.
- W2765508718 title "β-Lactam Synthesis through Diodomethane Addition to Amide Dianions" @default.
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- W2765508718 doi "https://doi.org/10.1002/anie.201706315" @default.
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