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- W2765666379 endingPage "345" @default.
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- W2765666379 abstract "Careful investigation of the effects of metal ions and pH value resulted in five multi-dimensional metal−organic complexes, [Co5(μ3-OH)2(α-bptc)2(H2O)6]n (1), {(H3O)2[Co4(μ3-O)(α-bptc)2(H2O)]·4H2O}n (2), {K2[Zn4(μ3-OH)2(α-bptc)2(H2O)3]}n (3), [Zn4(α-bptc)2(H2O)3]n (4), and {[Cd4(α-bptc)2(H2O)7]·2H2O}n (5) (α-H4bptc = 2,3,3',4'-biphenyl tetracarboxylic acid). The complexes consisted of different highly connected secondary building units (SBUs) assembled via hydrothermal in situ routes. The pH value as well as the kinds of metal ions influenced the coordination modes of α-H4bptc and also introduced the hydroxyl ligand at high pH value, resulting in the diversity of SBUs and dimensionality. Variable temperature magnetic measurements indicated the antiferromagnetic behavior in the Co5 core in 1, and the intra-chain ferrimagnetic behavior in complex 2. Moreover, the luminescent properties of the complexes 3−5 indicated the existence of intra-ligand charge transfer." @default.
- W2765666379 created "2017-11-10" @default.
- W2765666379 creator A5000390508 @default.
- W2765666379 creator A5002586734 @default.
- W2765666379 creator A5009815822 @default.
- W2765666379 creator A5029352950 @default.
- W2765666379 creator A5057078341 @default.
- W2765666379 date "2018-02-01" @default.
- W2765666379 modified "2023-10-14" @default.
- W2765666379 title "The diversity of five metal–organic complexes based on an unsymmetrical biphenyl tetracarboxylate: Synthesis, structures, magnetism and luminescence" @default.
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