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- W2765674299 abstract "Through comparing the linear and nonlinear optical property of two pull-push chromophores, which are composed of difluoroboron β-diketonate functionalized with carbazole and tert-butyl carbazole, the role of tert-butyl in chromosphere has been discussed in detail. The tert-butyl unit would lead to the absorption and fluorescence peak red shift and accelerate the fluorescence relaxation rate of chromophores. Moreover, the tert-butyl unit would affect obviously the two-photon optical property of chromophore according to the Z-scan test. The transient absorption (TA) data shows that these two pull-push chromopphores both own intramolecular charge transfer (ICT) characteristics and the tert-butyl unit accelerate the dynamic rate of ICT generation and relaxation process, which may be responsible for the variance of fluorescence property." @default.
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- W2765674299 date "2018-01-01" @default.
- W2765674299 modified "2023-10-15" @default.
- W2765674299 title "Role of tert-butyl in the linear and nonlinear optical property of push-pull chromophores" @default.
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- W2765674299 doi "https://doi.org/10.1016/j.jphotochem.2017.10.036" @default.
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