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- W2765818222 abstract "Jet and diesel fuels are typically composed of C9-C14 and C12-C20 hydrocarbons, respectively. However, the carbon-chain length of sugar-derived aldehydes and furanic compounds is no longer than C6. In the present study, a cascade catalytic process involving alkylation and hydrodeoxygenation (HDO) of 2-metylfuran (2-MF) with different aldehydes was conducted to directly produce long-chain alkanes with exclusive carbon number of C11-C17 in overall yields of 50-84%. Preliminary investigations on the alkylation of 2-MF and formalin illustrated that the relative density of Lewis and Bronsted acidic sites of zeolitic materials remarkably affected their catalytic activity and selectivity. Especially, Sn-beta(12.5) with pronounced Lewis acidity (including the acid density and strength) exhibited higher catalytic performance in the alkylation than other zeolites employed, giving long-chain oxygenates with 58-92% yields. Even in aqueous solution, the Sn-beta(12.5) catalyst could be reused for at least six reaction cycles with almost constant reactivity. More importantly, the co-addition of Hf(OTf)4 together with Pd/C was able to greatly promote C−O bond cleavage of the furan-ring during the HDO process under mild reaction conditions, giving long-chain alkanes with high yields of 84-94%." @default.
- W2765818222 created "2017-11-10" @default.
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- W2765818222 date "2018-04-06" @default.
- W2765818222 modified "2023-10-16" @default.
- W2765818222 title "Catalytic Tandem Reaction for the Production of Jet and Diesel Fuel Range Alkanes" @default.
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- W2765818222 doi "https://doi.org/10.1002/ente.201700637" @default.
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