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- W2765827767 abstract "An efficient, metal-free decarbethoxylative arylation protocol for the synthesis of α-aryl-α-fluoroamides from fluoromalonamates, under ambient reaction conditions using aryne as an electrophilic arylating agent, is reported. This decarbethoxylative arylation proceeds under mild conditions and provides a practical and effective entry to a wide range of α-aryl-α-fluoroacetamides. Interestingly, the use of the tert-butyl ester of fluoromalonamate prevented the otherwise rapid decarboxylation step, affording the arylated fluoromalonamate in moderate yield." @default.
- W2765827767 created "2017-11-10" @default.
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- W2765827767 date "2017-10-16" @default.
- W2765827767 modified "2023-10-02" @default.
- W2765827767 title "Decarbethoxylative Arylation Employing Arynes: A Metal-Free Pathway to Arylfluoroamides" @default.
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- W2765827767 doi "https://doi.org/10.1021/acs.orglett.7b03072" @default.
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