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- W2765954848 abstract "The asymmetric unit of the title compound, [Co(NCS) 2 (C 6 H 6 NS) 4 ]·CH 3 OH, consists of one cobalt(II) cation, two thiocyanate anions, four pyridine-4-carbothioamide ligands and one methanol molecule that are located in general positions. The Co II cations are coordinated by two terminal N-bonding thiocyanate anions and four N-bonding pyridine-4-carbothioamide ligands, resulting in discrete and slightly distorted octahedral complexes. These complexes are linked into a three-dimensional network via intermolecular N—H...S hydrogen bonding between the amino H atoms and the thiocyanate and pyridine-4-carbothioamide S atoms. From this arrangement, channels are formed in which the methanol solvate molecules are embedded and linked to the host structure by intermolecular O—H...S and N—H...O hydrogen bonding." @default.
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- W2765954848 date "2017-10-31" @default.
- W2765954848 modified "2023-09-24" @default.
- W2765954848 title "Crystal structure of bis(pyridine-4-carbothioamide-κN1)bis(thiocyanato-κN)cobalt(II) methanol monosolvate" @default.
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- W2765954848 doi "https://doi.org/10.1107/s2056989017015055" @default.
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