FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2765992108> ?p ?o ?g. }

• W2765992108 endingPage "219" @default.
• W2765992108 startingPage "212" @default.
• W2765992108 abstract "Abstract A new synthetic method has been developed for the efficient oxidation of alkynes into 1,2‐diketones by using a Pd II /Lewis acid catalytic system using DMSO as the oxidant and solvent. Under our optimized reaction conditions, this approach tolerated a variety of functional groups and afforded 1,2‐diketone derivatives in 62–99 % yields. This work demonstrated that the addition of non‐redox‐active metal ions, such as Al III , to Pd(OAc) 2 could dramatically improve its catalytic efficiency for alkyne oxidation, whilst reactions with Pd(OAc) 2 alone were sluggish and afforded a low yield of the corresponding diketone. Based on NMR and UV/Vis analysis, a heterobimetallic Pd II /Al III species was proposed for alkyne oxidation by adding AlCl 3 to Pd(OAc) 2 in DMSO. The catalytic efficiency of the Pd II species was improved by the linkage of Al III to the Pd II species, which made the Pd II species more electron deficient. This method may have the potential to become a simple, efficient procedure for the synthesis of 1,2‐diketone derivatives." @default.
• W2765992108 created "2017-11-10" @default.
• W2765992108 creator A5031336165 @default.
• W2765992108 creator A5049459654 @default.
• W2765992108 creator A5054565575 @default.
• W2765992108 creator A5073224102 @default.
• W2765992108 creator A5091291713 @default.
• W2765992108 date "2017-11-29" @default.
• W2765992108 modified "2023-09-30" @default.
• W2765992108 title "Catalytic Oxidation of Alkynes into 1,2-Diketone Derivatives by Using a Pd^II /Lewis-Acid Catalyst" @default.
• W2765992108 cites W1565752915 @default.
• W2765992108 cites W1640139249 @default.
• W2765992108 cites W1757031328 @default.
• W2765992108 cites W1970201408 @default.
• W2765992108 cites W1972220996 @default.
• W2765992108 cites W1976123775 @default.
• W2765992108 cites W1976542446 @default.
• W2765992108 cites W1982420107 @default.
• W2765992108 cites W1983589789 @default.
• W2765992108 cites W1984291726 @default.
• W2765992108 cites W1987307256 @default.
• W2765992108 cites W1988258885 @default.
• W2765992108 cites W1988498368 @default.
• W2765992108 cites W1992440040 @default.
• W2765992108 cites W1997470112 @default.
• W2765992108 cites W2003353130 @default.
• W2765992108 cites W2005578638 @default.
• W2765992108 cites W2007739859 @default.
• W2765992108 cites W2020109081 @default.
• W2765992108 cites W2020470590 @default.
• W2765992108 cites W2022348800 @default.
• W2765992108 cites W2026986910 @default.
• W2765992108 cites W2030973689 @default.
• W2765992108 cites W2032798411 @default.
• W2765992108 cites W2033879512 @default.
• W2765992108 cites W2034835602 @default.
• W2765992108 cites W2034918560 @default.
• W2765992108 cites W2034920754 @default.
• W2765992108 cites W2040689931 @default.
• W2765992108 cites W2043980033 @default.
• W2765992108 cites W2044571535 @default.
• W2765992108 cites W2055616260 @default.
• W2765992108 cites W2065362138 @default.
• W2765992108 cites W2068315901 @default.
• W2765992108 cites W2073730915 @default.
• W2765992108 cites W2074908429 @default.
• W2765992108 cites W2075777235 @default.
• W2765992108 cites W2083958020 @default.
• W2765992108 cites W2087950935 @default.
• W2765992108 cites W2089827803 @default.
• W2765992108 cites W2101373870 @default.
• W2765992108 cites W2120893740 @default.
• W2765992108 cites W2123639751 @default.
• W2765992108 cites W2123652858 @default.
• W2765992108 cites W2127925574 @default.
• W2765992108 cites W2135404424 @default.
• W2765992108 cites W2151756853 @default.
• W2765992108 cites W2160016102 @default.
• W2765992108 cites W2160423460 @default.
• W2765992108 cites W2170025667 @default.
• W2765992108 cites W2315515809 @default.
• W2765992108 cites W2318902122 @default.
• W2765992108 cites W2319586266 @default.
• W2765992108 cites W2320103343 @default.
• W2765992108 cites W2329889807 @default.
• W2765992108 cites W2329997456 @default.
• W2765992108 cites W2334665527 @default.
• W2765992108 cites W2414491919 @default.
• W2765992108 cites W2467348854 @default.
• W2765992108 cites W2519903985 @default.
• W2765992108 cites W2556333647 @default.
• W2765992108 cites W2562447737 @default.
• W2765992108 cites W2607066010 @default.
• W2765992108 cites W2747564563 @default.
• W2765992108 cites W2950270362 @default.
• W2765992108 cites W2951039099 @default.
• W2765992108 cites W2951500947 @default.
• W2765992108 cites W2951712078 @default.
• W2765992108 cites W2952205941 @default.
• W2765992108 cites W2953237953 @default.
• W2765992108 cites W2953331018 @default.
• W2765992108 cites W4249821620 @default.
• W2765992108 cites W4254294356 @default.
• W2765992108 cites W4379363652 @default.
• W2765992108 doi "https://doi.org/10.1002/ajoc.201700556" @default.
• W2765992108 hasPublicationYear "2017" @default.
• W2765992108 type Work @default.
• W2765992108 sameAs 2765992108 @default.
• W2765992108 citedByCount "22" @default.
• W2765992108 countsByYear W27659921082018 @default.
• W2765992108 countsByYear W27659921082019 @default.
• W2765992108 countsByYear W27659921082020 @default.
• W2765992108 countsByYear W27659921082021 @default.
• W2765992108 countsByYear W27659921082022 @default.
• W2765992108 countsByYear W27659921082023 @default.
• W2765992108 crossrefType "journal-article" @default.
• W2765992108 hasAuthorship W2765992108A5031336165 @default.
• W2765992108 hasAuthorship W2765992108A5049459654 @default.

• next