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- W2766113844 abstract "LBNL-58757 LSM-YSZ CATHODES WITH REACTION-INFILTRATED NANOPARTICLES Chun Lu 1 , Tal Z. Sholklapper 1, 2 , Craig P. Jacobson 1 , Steven J. Visco 1 , and Lutgard C. De Jonghe 1, 2 Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley, CA 94720 and Materials Science and Engineering Department University of California at Berkeley Berkeley CA 94720 ABSTRACT To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm 0.6 Sr 0.4 CoO 3-δ (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are ~20 to 80nm in diameter, and intimately adhere to the pore walls of the pre-formed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97%H 2 +3%H 2 O fuel, between 600 o C and 800 o C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed." @default.
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- W2766113844 date "2006-01-31" @default.
- W2766113844 modified "2023-09-27" @default.
- W2766113844 title "LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles - eScholarship" @default.
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