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- W2766124543 abstract "Abstract The electrochemistry of several ruthenium porphyrin nitrosyl chloride complexes [Ru(por)(NO)Cl] have been examined in tetrahydrofuran (THF). The complexes undergo one‐electron irreversible reductions, which result in diffusion‐limited substitutions of the chloride ligands for THF. This chloride metathesis is reversible in the presence of added NBu 4 Cl, and equilibrium constants and rate constants for chloride loss have been estimated. These parameters correlate with the NO stretching frequencies of the parent complexes, with more electron‐donating porphyrin ligands favoring chloride loss from the reduced complexes. The [Ru(por)(NO)(THF)] products of the reductions can be detected by IR, EPR, and visible spectroscopies. These species undergo three further reductions, with good reversibility at scan rates >0.40 V s −1 . The [Ru(por) (NO)(THF)] +/0 couples have also been determined, and the rate constants and equilibrium constants for recombination with chloride have been estimated. One‐electron reductions of the [Ru(por)(NO)Cl] complexes result in approximately 10 18 enhancement of the rates of chloride loss." @default.
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- W2766124543 date "2017-11-29" @default.
- W2766124543 modified "2023-09-25" @default.
- W2766124543 title "Electrochemical Investigation of the Kinetics of Chloride Substitution upon Reduction of [Ru(porphyrin)(NO)Cl] Complexes in Tetrahydrofuran" @default.
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- W2766124543 doi "https://doi.org/10.1002/celc.201701001" @default.
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