Matches in SemOpenAlex for { <https://semopenalex.org/work/W2766156972> ?p ?o ?g. }
- W2766156972 endingPage "16973" @default.
- W2766156972 startingPage "16967" @default.
- W2766156972 abstract "The conversion of carbon monoxide (CO) to hydrocarbons and oxygenates on industrial solid catalysts (the Fischer-Tropsch reaction) largely relies on the cooperation of heteromultimetallic active sites composed of main group (such as alkali) and transition metals, but the mechanistic details have not been fully understood at the molecular level. Here we report the cooperative trimerization of CO by molecular lithium and samarium boryl complexes. We have found that, in the coexistence of a samarium boryl complex and a lithium boryl complex, the trimerization of CO selectively occurred to give a diborylallenetriolate skeleton BC(O)C(O)C(O)B, in sharp contrast with the reaction of CO with either the lithium or the samarium boryl compound alone. The 13C-labeled experiments and computational studies have revealed that the CO trimerization reaction took place exclusively by coupling of a samarium boryl oxycarbene species, which was generated by insertion of one molecule of CO into the samarium-boryl bond, with a lithium ketenolate species formed by insertion of two molecules of CO into the lithium-boryl bond. These results offer unprecedented insight into CO oligomerization promoted by heteromultimetallic components and may help better understand the industrial F-T process and guide designing new catalysts." @default.
- W2766156972 created "2017-11-10" @default.
- W2766156972 creator A5008037802 @default.
- W2766156972 creator A5011196991 @default.
- W2766156972 creator A5046378812 @default.
- W2766156972 creator A5059749118 @default.
- W2766156972 creator A5075916046 @default.
- W2766156972 date "2017-11-08" @default.
- W2766156972 modified "2023-10-15" @default.
- W2766156972 title "Cooperative Trimerization of Carbon Monoxide by Lithium and Samarium Boryls" @default.
- W2766156972 cites W1567326385 @default.
- W2766156972 cites W1938642766 @default.
- W2766156972 cites W1964058519 @default.
- W2766156972 cites W1971249591 @default.
- W2766156972 cites W1972394856 @default.
- W2766156972 cites W1974001124 @default.
- W2766156972 cites W1983794742 @default.
- W2766156972 cites W1988306724 @default.
- W2766156972 cites W1995387931 @default.
- W2766156972 cites W2001293719 @default.
- W2766156972 cites W2002115308 @default.
- W2766156972 cites W2002427808 @default.
- W2766156972 cites W2003182184 @default.
- W2766156972 cites W2014458124 @default.
- W2766156972 cites W2022702100 @default.
- W2766156972 cites W2023981305 @default.
- W2766156972 cites W2029441969 @default.
- W2766156972 cites W2032581014 @default.
- W2766156972 cites W2045903488 @default.
- W2766156972 cites W2050105495 @default.
- W2766156972 cites W2051234031 @default.
- W2766156972 cites W2055393736 @default.
- W2766156972 cites W2055662875 @default.
- W2766156972 cites W2058971335 @default.
- W2766156972 cites W2064414363 @default.
- W2766156972 cites W2067638943 @default.
- W2766156972 cites W2077963621 @default.
- W2766156972 cites W2089009237 @default.
- W2766156972 cites W2090519417 @default.
- W2766156972 cites W2094056928 @default.
- W2766156972 cites W2127942243 @default.
- W2766156972 cites W2142082843 @default.
- W2766156972 cites W2171093181 @default.
- W2766156972 cites W2198324263 @default.
- W2766156972 cites W2199995433 @default.
- W2766156972 cites W2226279316 @default.
- W2766156972 cites W2252438735 @default.
- W2766156972 cites W2312740546 @default.
- W2766156972 cites W2325288593 @default.
- W2766156972 cites W2347053637 @default.
- W2766156972 cites W2351875592 @default.
- W2766156972 cites W2573996428 @default.
- W2766156972 cites W2949254338 @default.
- W2766156972 cites W2949533998 @default.
- W2766156972 cites W2952068096 @default.
- W2766156972 cites W2952450016 @default.
- W2766156972 cites W2953270166 @default.
- W2766156972 cites W323561414 @default.
- W2766156972 cites W4254254078 @default.
- W2766156972 cites W4376849724 @default.
- W2766156972 cites W968693410 @default.
- W2766156972 doi "https://doi.org/10.1021/jacs.7b10108" @default.
- W2766156972 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29083923" @default.
- W2766156972 hasPublicationYear "2017" @default.
- W2766156972 type Work @default.
- W2766156972 sameAs 2766156972 @default.
- W2766156972 citedByCount "46" @default.
- W2766156972 countsByYear W27661569722018 @default.
- W2766156972 countsByYear W27661569722019 @default.
- W2766156972 countsByYear W27661569722020 @default.
- W2766156972 countsByYear W27661569722021 @default.
- W2766156972 countsByYear W27661569722022 @default.
- W2766156972 countsByYear W27661569722023 @default.
- W2766156972 crossrefType "journal-article" @default.
- W2766156972 hasAuthorship W2766156972A5008037802 @default.
- W2766156972 hasAuthorship W2766156972A5011196991 @default.
- W2766156972 hasAuthorship W2766156972A5046378812 @default.
- W2766156972 hasAuthorship W2766156972A5059749118 @default.
- W2766156972 hasAuthorship W2766156972A5075916046 @default.
- W2766156972 hasConcept C134018914 @default.
- W2766156972 hasConcept C161790260 @default.
- W2766156972 hasConcept C178790620 @default.
- W2766156972 hasConcept C179104552 @default.
- W2766156972 hasConcept C185592680 @default.
- W2766156972 hasConcept C194439259 @default.
- W2766156972 hasConcept C2778541603 @default.
- W2766156972 hasConcept C32909587 @default.
- W2766156972 hasConcept C512735826 @default.
- W2766156972 hasConcept C536819264 @default.
- W2766156972 hasConcept C71924100 @default.
- W2766156972 hasConceptScore W2766156972C134018914 @default.
- W2766156972 hasConceptScore W2766156972C161790260 @default.
- W2766156972 hasConceptScore W2766156972C178790620 @default.
- W2766156972 hasConceptScore W2766156972C179104552 @default.
- W2766156972 hasConceptScore W2766156972C185592680 @default.
- W2766156972 hasConceptScore W2766156972C194439259 @default.
- W2766156972 hasConceptScore W2766156972C2778541603 @default.
- W2766156972 hasConceptScore W2766156972C32909587 @default.