Matches in SemOpenAlex for { <https://semopenalex.org/work/W2766165858> ?p ?o ?g. }
- W2766165858 endingPage "25502" @default.
- W2766165858 startingPage "25494" @default.
- W2766165858 abstract "Optical activity (OA) along the optic axis of crystalline benzil has been measured by many over the past 150 years. However, the OA anisotropy remains uncharacterized due to difficulties in sample preparation as well as competition with linear birefringence (LB). The challenges associated with measuring OA along low-symmetry directions in crystals have too often left scientists with only average values of nonresonant OA in solution, i.e., specific rotations, which continue to resist interpretation in terms of structure. Measuring OA anisotropy has been facilitated by recent advances in polarimetry and optical modeling and here we compare results from two distinct division-of-time polarimeters. The absolute structure of crystalline benzil was established for the first time. The optical rotation (OR) of (+)-crystalline benzil (space group P3121) perpendicular to the optic axis at the sodium D-line is −24.6 ± 1.1°/mm. A spectroscopic optical model in the transparent region of the crystal is provided. Electronic structure calculations of OR inform the polarimetric measurements and point to the necessity of developing linear response theory with periodic boundary conditions in order to interpret the results of chiroptical measurements in crystals." @default.
- W2766165858 created "2017-11-10" @default.
- W2766165858 creator A5010067834 @default.
- W2766165858 creator A5030820766 @default.
- W2766165858 creator A5038488218 @default.
- W2766165858 creator A5051674145 @default.
- W2766165858 creator A5052669726 @default.
- W2766165858 creator A5065089297 @default.
- W2766165858 date "2017-11-07" @default.
- W2766165858 modified "2023-09-25" @default.
- W2766165858 title "Optical Activity Anisotropy of Benzil" @default.
- W2766165858 cites W120724380 @default.
- W2766165858 cites W1499218427 @default.
- W2766165858 cites W1520537530 @default.
- W2766165858 cites W1556643700 @default.
- W2766165858 cites W1623767674 @default.
- W2766165858 cites W1965142221 @default.
- W2766165858 cites W1965605147 @default.
- W2766165858 cites W1965779954 @default.
- W2766165858 cites W1967812528 @default.
- W2766165858 cites W1969212973 @default.
- W2766165858 cites W1975321641 @default.
- W2766165858 cites W1978298545 @default.
- W2766165858 cites W1978691610 @default.
- W2766165858 cites W1978792983 @default.
- W2766165858 cites W1980992775 @default.
- W2766165858 cites W1984081565 @default.
- W2766165858 cites W1992913693 @default.
- W2766165858 cites W1995494636 @default.
- W2766165858 cites W1998093588 @default.
- W2766165858 cites W1998475915 @default.
- W2766165858 cites W2001633234 @default.
- W2766165858 cites W2002251135 @default.
- W2766165858 cites W2011454034 @default.
- W2766165858 cites W2022672927 @default.
- W2766165858 cites W2024392559 @default.
- W2766165858 cites W2024586837 @default.
- W2766165858 cites W2025558028 @default.
- W2766165858 cites W2027010328 @default.
- W2766165858 cites W2028337683 @default.
- W2766165858 cites W2030730998 @default.
- W2766165858 cites W2035528548 @default.
- W2766165858 cites W2038333089 @default.
- W2766165858 cites W2039597795 @default.
- W2766165858 cites W2040175513 @default.
- W2766165858 cites W2040212502 @default.
- W2766165858 cites W2040474870 @default.
- W2766165858 cites W2040886285 @default.
- W2766165858 cites W2042401086 @default.
- W2766165858 cites W2042460881 @default.
- W2766165858 cites W2050051207 @default.
- W2766165858 cites W2051723371 @default.
- W2766165858 cites W2057212226 @default.
- W2766165858 cites W2063166222 @default.
- W2766165858 cites W2065040115 @default.
- W2766165858 cites W2065584748 @default.
- W2766165858 cites W2066085660 @default.
- W2766165858 cites W2072410884 @default.
- W2766165858 cites W2073254866 @default.
- W2766165858 cites W2073492695 @default.
- W2766165858 cites W2081249906 @default.
- W2766165858 cites W2084158712 @default.
- W2766165858 cites W2087653653 @default.
- W2766165858 cites W2089102597 @default.
- W2766165858 cites W2089249221 @default.
- W2766165858 cites W2089578419 @default.
- W2766165858 cites W2093645094 @default.
- W2766165858 cites W2099321807 @default.
- W2766165858 cites W2101717721 @default.
- W2766165858 cites W2106338082 @default.
- W2766165858 cites W2106582407 @default.
- W2766165858 cites W2113820019 @default.
- W2766165858 cites W2122040303 @default.
- W2766165858 cites W2131549533 @default.
- W2766165858 cites W2170803916 @default.
- W2766165858 cites W2235370295 @default.
- W2766165858 cites W2315326604 @default.
- W2766165858 cites W2318607959 @default.
- W2766165858 cites W2320135801 @default.
- W2766165858 cites W2409624442 @default.
- W2766165858 cites W2474136730 @default.
- W2766165858 cites W2498741221 @default.
- W2766165858 cites W2520504420 @default.
- W2766165858 cites W2535796534 @default.
- W2766165858 cites W2581605667 @default.
- W2766165858 cites W2591289959 @default.
- W2766165858 cites W2737627826 @default.
- W2766165858 cites W2952996493 @default.
- W2766165858 cites W4235963640 @default.
- W2766165858 cites W62702106 @default.
- W2766165858 cites W2532792919 @default.
- W2766165858 doi "https://doi.org/10.1021/acs.jpcc.7b08831" @default.
- W2766165858 hasPublicationYear "2017" @default.
- W2766165858 type Work @default.
- W2766165858 sameAs 2766165858 @default.
- W2766165858 citedByCount "9" @default.
- W2766165858 countsByYear W27661658582018 @default.
- W2766165858 countsByYear W27661658582019 @default.