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• W2766260849 startingPage "6781" @default.
• W2766260849 abstract "We report the first stereoselective synthesis of (2 R ,3a R ,7a R )‐ and (2 S ,3a S ,7a S )‐octahydroindole‐2‐phosphonic acid 2 (Oic P derivatives). The key points are the highly diastereoselective synthesis of cis ‐fused bicyclic (3a R ,7a R )‐ and (3a S ,7a S )‐pyrrolidin‐2‐ones 4 through a dynamic kinetic resolution of racemic γ‐keto acid (±)‐ 5 with ( R )‐ and ( S )‐phenylglycinol via Meyers' bicyclic lactams, and the highly diastereoselective addition of trimethyl phosphite to the N ‐acyliminium ions 3 obtained from 4 ." @default.
• W2766260849 created "2017-11-10" @default.
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• W2766260849 date "2017-11-30" @default.
• W2766260849 modified "2023-10-02" @default.
• W2766260849 title "First and Highly Stereoselective Synthesis of Both Enantiomers of Octahydroindole-2-phosphonic Acid (Oic^P)" @default.
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• W2766260849 doi "https://doi.org/10.1002/ejoc.201701330" @default.
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