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• W2766497396 startingPage "5876" @default.
• W2766497396 abstract "By using Co(acac)2/Xantphos with AlMe3, the C(sp3)–H bonds of allylarene derivatives were cleaved for reaction with various ketones, affording the homoallylic alcohols in moderate to good yields. The branch/linear selectivity depended on the steric and electronic factors of the ketone electrophiles. The intermediate in this reaction is thought to be a low-valent allylcobalt(I) species, which exhibits high nucleophilicity toward ketones." @default.
• W2766497396 created "2017-11-10" @default.
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• W2766497396 date "2017-10-19" @default.
• W2766497396 modified "2023-10-16" @default.
• W2766497396 title "Co-Catalyzed Direct Addition of Allylic C(sp³)–H Bonds to Ketones" @default.
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• W2766497396 doi "https://doi.org/10.1021/acs.orglett.7b02871" @default.
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