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- W2766511045 endingPage "16394" @default.
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- W2766511045 abstract "Abstract Aryl and heteroaryl halides (X=Br, I) undergo a fast and convenient halogen–lanthanum exchange with nBu 2 LaMe, which leads to functionalized diaryl‐ and diheteroaryllanthanum derivatives. Subsequent trapping reactions with selected electrophiles, such as ketones, aldehydes, or amides, proceeded smoothly at −50 °C in THF, affording polyfunctionalized alcohols and carbonyl derivatives. Kinetic competition experiments revealed a similar reactivity trend as for Br/Mg exchange, but 10 6 ‐times higher rates, making it comparable to Br/Li exchange." @default.
- W2766511045 created "2017-11-10" @default.
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- W2766511045 date "2017-11-22" @default.
- W2766511045 modified "2023-10-12" @default.
- W2766511045 title "Preparation of Functionalized Diaryl- and Diheteroaryllanthanum Reagents by Fast Halogen-Lanthanum Exchange" @default.
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- W2766511045 doi "https://doi.org/10.1002/anie.201709553" @default.
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