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- W2766655217 abstract "Two new pentaborates, trisodium zinc cadmium pentaborate, Na 3 Zn 0.912 Cd 0.088 B 5 O 10 , and trisodium zinc magnesium pentaborate, Na 3 Zn 0.845 Mg 0.155 B 5 O 10 , have been synthesized by high-temperature solution reactions at 1023 K. Their crystal structures were determined by single-crystal X-ray diffraction. Both solid solutions crystallize in the orthorhombic form of the parent compound Na 3 ZnB 5 O 10 (space group type Pbca , Z = 8) and contain the double ring [B 5 O 10 ] 5− anion composed of one BO 4 tetrahedron and four BO 3 triangles as the basic structural motif. The anions are bridged by tetrahedrally coordinated and occupationally disordered M 2+ ( M = Zn/Cd, Zn/Mg) cations via common O atoms to form [ M B 5 O 10 ] n 3 n − layers. The intralayer intersecting channels and the interlayer voids are occupied by Na + cations to balance the charge." @default.
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- W2766655217 date "2017-10-24" @default.
- W2766655217 modified "2023-09-24" @default.
- W2766655217 title "Crystal structures of the solid solutions Na3Zn0.912Cd0.088B5O10and Na3Zn0.845Mg0.155B5O10" @default.
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- W2766655217 doi "https://doi.org/10.1107/s2056989017015249" @default.
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