Matches in SemOpenAlex for { <https://semopenalex.org/work/W2766697681> ?p ?o ?g. }
- W2766697681 endingPage "9029" @default.
- W2766697681 startingPage "9023" @default.
- W2766697681 abstract "The electrolyte is a crucial component of lithium–sulfur (Li–S) batteries, as it controls polysulfide dissolution, charge shuttling processes, and solid-electrolyte interphase (SEI) layer formation. Experimentally, the overall performance of Li–S batteries varies with choice of solvent system and Li-salt used in the electrolyte, and a lack of predictive understanding about the effects of individual electrolyte components inhibits the rational design of electrolytes for Li–S batteries. Here we analyze the role of the counteranions of common Li salts (such as TfO–, FSI–, TFSI–, and TDI–) when dissolved in DOL/DME (1:1 by vol.) for use in Li–S batteries. The evolution of ion–ion and ion–solvent interactions due to various anions was analyzed using 17O NMR and pulsed-field gradient (PFG) NMR and then correlated with electrochemical performance in Li–S cells. These data reveal that the formation of the passivation layer on the anode and the loss of active materials from the cathode (evidenced by polysulfide dissolution) are related to anion mobility and affinity with lithium polysulfide, respectively. For future electrolyte design, anions with lower mobility and weaker interactions with lithium polysulfides may be superior candidates for increasing the long-term stability of Li–S batteries." @default.
- W2766697681 created "2017-11-10" @default.
- W2766697681 creator A5017114657 @default.
- W2766697681 creator A5023805248 @default.
- W2766697681 creator A5028409726 @default.
- W2766697681 creator A5032583158 @default.
- W2766697681 creator A5037535334 @default.
- W2766697681 creator A5044356586 @default.
- W2766697681 creator A5047801680 @default.
- W2766697681 creator A5048752016 @default.
- W2766697681 creator A5049626346 @default.
- W2766697681 creator A5064389955 @default.
- W2766697681 date "2017-10-27" @default.
- W2766697681 modified "2023-10-16" @default.
- W2766697681 title "Effects of Anion Mobility on Electrochemical Behaviors of Lithium–Sulfur Batteries" @default.
- W2766697681 cites W1970905334 @default.
- W2766697681 cites W1977598985 @default.
- W2766697681 cites W1984147471 @default.
- W2766697681 cites W1987206449 @default.
- W2766697681 cites W1995513247 @default.
- W2766697681 cites W2014155497 @default.
- W2766697681 cites W2056620288 @default.
- W2766697681 cites W2087078846 @default.
- W2766697681 cites W2094832887 @default.
- W2766697681 cites W2124844594 @default.
- W2766697681 cites W2125658152 @default.
- W2766697681 cites W2134363353 @default.
- W2766697681 cites W2147718835 @default.
- W2766697681 cites W2313379660 @default.
- W2766697681 cites W2315657475 @default.
- W2766697681 cites W2321770148 @default.
- W2766697681 cites W2322001877 @default.
- W2766697681 cites W2324643696 @default.
- W2766697681 cites W2325327503 @default.
- W2766697681 cites W2327810915 @default.
- W2766697681 cites W2482083820 @default.
- W2766697681 cites W2738016307 @default.
- W2766697681 cites W4211209602 @default.
- W2766697681 doi "https://doi.org/10.1021/acs.chemmater.7b02105" @default.
- W2766697681 hasPublicationYear "2017" @default.
- W2766697681 type Work @default.
- W2766697681 sameAs 2766697681 @default.
- W2766697681 citedByCount "33" @default.
- W2766697681 countsByYear W27666976812018 @default.
- W2766697681 countsByYear W27666976812019 @default.
- W2766697681 countsByYear W27666976812020 @default.
- W2766697681 countsByYear W27666976812021 @default.
- W2766697681 countsByYear W27666976812022 @default.
- W2766697681 countsByYear W27666976812023 @default.
- W2766697681 crossrefType "journal-article" @default.
- W2766697681 hasAuthorship W2766697681A5017114657 @default.
- W2766697681 hasAuthorship W2766697681A5023805248 @default.
- W2766697681 hasAuthorship W2766697681A5028409726 @default.
- W2766697681 hasAuthorship W2766697681A5032583158 @default.
- W2766697681 hasAuthorship W2766697681A5037535334 @default.
- W2766697681 hasAuthorship W2766697681A5044356586 @default.
- W2766697681 hasAuthorship W2766697681A5047801680 @default.
- W2766697681 hasAuthorship W2766697681A5048752016 @default.
- W2766697681 hasAuthorship W2766697681A5049626346 @default.
- W2766697681 hasAuthorship W2766697681A5064389955 @default.
- W2766697681 hasConcept C127413603 @default.
- W2766697681 hasConcept C134018914 @default.
- W2766697681 hasConcept C145148216 @default.
- W2766697681 hasConcept C147789679 @default.
- W2766697681 hasConcept C17525397 @default.
- W2766697681 hasConcept C178790620 @default.
- W2766697681 hasConcept C179104552 @default.
- W2766697681 hasConcept C185592680 @default.
- W2766697681 hasConcept C2776371256 @default.
- W2766697681 hasConcept C2777379467 @default.
- W2766697681 hasConcept C2778541603 @default.
- W2766697681 hasConcept C2779227376 @default.
- W2766697681 hasConcept C2780471494 @default.
- W2766697681 hasConcept C33574316 @default.
- W2766697681 hasConcept C42360764 @default.
- W2766697681 hasConcept C49110097 @default.
- W2766697681 hasConcept C518881349 @default.
- W2766697681 hasConcept C52859227 @default.
- W2766697681 hasConcept C68801617 @default.
- W2766697681 hasConcept C71924100 @default.
- W2766697681 hasConcept C88380143 @default.
- W2766697681 hasConcept C89395315 @default.
- W2766697681 hasConceptScore W2766697681C127413603 @default.
- W2766697681 hasConceptScore W2766697681C134018914 @default.
- W2766697681 hasConceptScore W2766697681C145148216 @default.
- W2766697681 hasConceptScore W2766697681C147789679 @default.
- W2766697681 hasConceptScore W2766697681C17525397 @default.
- W2766697681 hasConceptScore W2766697681C178790620 @default.
- W2766697681 hasConceptScore W2766697681C179104552 @default.
- W2766697681 hasConceptScore W2766697681C185592680 @default.
- W2766697681 hasConceptScore W2766697681C2776371256 @default.
- W2766697681 hasConceptScore W2766697681C2777379467 @default.
- W2766697681 hasConceptScore W2766697681C2778541603 @default.
- W2766697681 hasConceptScore W2766697681C2779227376 @default.
- W2766697681 hasConceptScore W2766697681C2780471494 @default.
- W2766697681 hasConceptScore W2766697681C33574316 @default.
- W2766697681 hasConceptScore W2766697681C42360764 @default.
- W2766697681 hasConceptScore W2766697681C49110097 @default.