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- W2766762735 endingPage "1902" @default.
- W2766762735 startingPage "1902" @default.
- W2766762735 abstract "Solid-state functional luminescent materials arouse an enormous scientific interest due to their diverse applications in lighting, display devices, photonics, optical communication, low energy scintillation, optical storage, light conversion, or photovoltaics. Among all types of solid luminophors, the emissive coordination polymers, especially those based on luminescent trivalent lanthanide ions, exhibit a particularly large scope of light-emitting functionalities, fruitfully investigated in the aspects of chemical sensing, display devices, and bioimaging. Here, we present the complete overview of one of the promising families of photoluminescent coordination compounds, that are heterometallic d–f cyanido-bridged networks composed of lanthanide(3+) ions connected through cyanide bridges with polycyanidometallates of d-block metal ions. We are showing that the combination of cationic lanthanide complexes of selected inorganic and organic ligands with anionic homoligand [M(CN)x]n− (x = 2, 4, 6 and 8) or heteroligand [M(L)(CN)4]2− (L = bidentate organic ligand, M = transition metal ions) anions is the efficient route towards the emissive coordination networks revealing important optical properties, including 4f-metal-centred visible and near-infrared emission sensitized through metal-to-metal and/or ligand-to-metal energy transfer processes, and multi-coloured photoluminescence switchable by external stimuli such as excitation wavelength, temperature, or pressure." @default.
- W2766762735 created "2017-11-10" @default.
- W2766762735 creator A5058572222 @default.
- W2766762735 creator A5072941372 @default.
- W2766762735 creator A5084109491 @default.
- W2766762735 date "2017-11-04" @default.
- W2766762735 modified "2023-10-13" @default.
- W2766762735 title "Lanthanide Photoluminescence in Heterometallic Polycyanidometallate-Based Coordination Networks" @default.
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