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- W2766887593 abstract "Spectroscopy under isolated conditions at low temperatures is an excellent tool to characterize the aggregates stabilized through weak interactions. Within the framework of weak interactions, the π-stacking interactions are considered unconventional with the limited experimental proofs, wherein the bonding associates are either aromatic and heterocyclic compounds or their combinations. Besides aromatic compounds, π-stacking networks can even be realized with molecules possessing electron rich π-clouds. In this work, the N2 molecule as a possible π-bonding partner is explored for the first time in which hetero π-stacking was achieved between pyrrole and N2 precursors. The matrix isolation experiments performed by seeding pyrrole and N2 mixtures in an Ar matrix at low temperatures with subsequent infrared spectral characterization revealed the generation of adducts stabilized through a π(pyrrole)···π(N2) interaction. Under identical conditions with the likelihood of two competing π-stacking and hydrogen-bonding interactions in pyrrole–N2 associates, π-stacking dominates energetically over hydrogen-bonding interaction." @default.
- W2766887593 created "2017-11-10" @default.
- W2766887593 creator A5014080059 @default.
- W2766887593 creator A5028199525 @default.
- W2766887593 creator A5068526397 @default.
- W2766887593 date "2017-11-15" @default.
- W2766887593 modified "2023-09-27" @default.
- W2766887593 title "Nitrogen: A New Class of π-Bonding Partner in Hetero π-Stacking Interaction" @default.
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- W2766887593 doi "https://doi.org/10.1021/acs.jpca.7b08164" @default.
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