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• W2766988729 abstract "Water in oil in water (WOW) double emulsions have a great potential as encapsulation systems in different industrial sections. Nevertheless, there are only few double emulsion based products available on market. An important limitation, regarding the product launch, is the insufficient stability of these products. Many instability mechanisms have to be taken into account: coalescence between inner water droplets, coalescence between outer oil droplets, coalescence between inner and outer water phase, and diffusion between the dispersed water droplets and the continuous outer water phase. In the present study, we focus on structural changes and stabilization mechanisms of inner water in oil (WO) emulsions. Osmotic active substances (OAS) have to be used in the inner water droplets to limit the diffusion processes between the water phases in double emulsions. We therefore investigated the influence of different OAS on the structural changes in WO emulsions. We focused on three subprocesses influencing the emulsification result: droplet breakup, stabilization directly after breakup and diffusional processes after droplet stabilization. For this, we prepared WO emulsions using sodium chloride, calcium chloride and glucose as OAS and polyglycerine-polyricinoleate as lipophilic emulsifier. The droplet size distribution was determined to evaluate structural changes. Furthermore, we measured interfacial properties and emulsion viscosities to evaluate stabilizing effects. Kinetic stabilization effects were evaluated by applying high pressure homogenization, known as a process with high requirements on the stabilization efficiency. The osmolality of the inner water phases was determined as parameter for the likelihood of diffusional processes. This characteristic value strongly depends on OAS type and concentration. Adsorption kinetics and diffusional processes turned out as the main factors influencing inner emulsion structure." @default.
• W2766988729 created "2017-11-10" @default.
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• W2766988729 date "2018-02-01" @default.
• W2766988729 modified "2023-09-27" @default.
• W2766988729 title "Investigations on the influence of osmotic active substances on the structure of water in oil emulsions for the application as inner phase in double emulsions" @default.
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• W2766988729 doi "https://doi.org/10.1016/j.colsurfa.2017.10.073" @default.
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